methylammonium iodide

methylammonium iodide
  • CAS No.:14965-49-2
Other grades of this product :

methylammonium iodide Basic information
Specifications Applications
Product Name:methylammonium iodide
Synonyms:MAI;LT-S9126;methylammonium iodide;Methylamine·hydriodic acid;CH3NH3I (MAI);MethylazaniuM;Methanamine hydriodide;Methylamine Hydroiodide
CAS:14965-49-2
MF:CH6IN
MW:158.96951
EINECS:239-037-4
Product Categories:
Mol File:14965-49-2.mol
methylammonium iodide Chemical Properties
Melting point 270-280°C
Fp 12℃
storage temp. Hygroscopic, Refrigerator, under inert atmosphere
solubility Methanol (Slightly), Water
form powder
color White to Off-White
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 26-36/37/39-46-24/25
RIDADR UN1219 - class 3 - PG 2 - Isopropanol
WGK Germany 3
HS Code 29211100
MSDS Information
methylammonium iodide Usage And Synthesis
Specifications

Chemical formula

CH6IN

Synonyms

Methylamine hydroiodide

CAS No.

14965-49-2

Chemical name

Methylammonium iodide

Physical appearance

White, crystalline solid

Purification method

Recrystallisation (ethanol)

Purity

>99.9% (as measured by elemental analysis)

Molecular weight

158.97 g/mol

Recommended solvents for perovskite synthesis

DMF, DMSO

ApplicationsMethylammonium iodide (MAI), also referred to as methylamine hydroiodide, is a precursor for the synthesis of organic-inorganic hybrid perovskites for use in FETs, LEDs and PVs. Due to the high purity of the methylammonium iodide (99.99%), it should be noted that its solubility is reduced within dimethyl formamide and dimethyl sulfoxide. This reduced solubility is due to the removal of trace amounts of residual hydroiodic acid (HI) used during the synthesis and purification of the material. This can potentially have an impact upon the performance of solar cells leading to a reduction in maximum power conversion efficiency achievable. Adding fixed concentrations of hydroiodic acid to perovskite solutions can allow for the improvement of device metrics. Using high-purity precursor materials allows for accurate addition of amounts of hydroiodic acid giving higher reproducibility to experiments. It is recommended that between 1% and 10% hydroiodic acid is used with high-purity methylammonium iodide to achieve optimal device performance. The amount required depends on the precursors used, solution concentration, solvent used, and processing environment. Therefore, this will need to be adjusted for each individual laboratory and process.
Application

For simpler ink fabrication, it is recommended that the lower-purity methylammonium iodide (>98%) is used.

DescriptionMethylammonium iodide (MAI), also referred to as methylamine hydroiodide,?is a precursor for the synthesis of organic-inorganic hybrid perovskites for use in FETs, LEDs and PVs.
UsesMethylammonium iodide can be used as a precursor in combination with lead iodide to change the morphology of the resulting perovskite materials. Perovskite materials can further be utilized in the fabrication of alternative energy devices such as light emitting diodes (LEDs), and perovskite solar cells (PSCs).
UsesOrganohalide based perovskites have emerged as an important class of material for solar cell applications. Our perovskites precursors with extremely low water contents are useful for synthesizing mixed cation or anion perovskites needed for the optimization of the band gap, carrier diffusion length and power conversion efficiency of perovskites based solar cells.
UsesThe iodide and bromide based alkylated halides find applications as precursors for fabrication of perovskites for photovoltaic applications.
methylammonium iodide Preparation Products And Raw materials
Raw materialsHydriodic acid
Preparation ProductsPerovskite CH3NH3PbI3 Powder

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