2-Chloroanisole

CAS No.：766-51-8

Other grades of this product :

2-Chloroanisole Basic information

Product Name:	2-Chloroanisole
Synonyms:	1-chloro-2-methoxy-benzen;2-chloromethoxybenzene;2-Chlorophenol methyl ether;Anisole, o-chloro-;Adjacent chlorobenzene Methoxy;2-Chloroanisol;anisole,o-chloro-;benzene,1-chloro-2-methoxy-
CAS:	766-51-8
MF:	C7H7ClO
MW:	142.58
EINECS:	212-167-9
Product Categories:	Building Blocks;C2 to C7;Aromatic Ethers;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds;Anisole;Anisoles, Alkyloxy Compounds & Phenylacetates;Chlorine Compounds;Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:	766-51-8.mol

2-Chloroanisole Chemical Properties

Melting point	-26.8°C
Boiling point	195-196 °C (lit.)
density	1.123 g/mL at 25 °C (lit.)
refractive index	n20/D 1.545(lit.)
Fp	169 °F
storage temp.	Sealed in dry,Room Temperature
form	Liquid
color	Clear light yellow
Water Solubility	0.49g/L(25 ºC)
BRN	2042179
CAS DataBase Reference	766-51-8(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-chloro-2-methoxy-(766-51-8)
EPA Substance Registry System	o-Chloroanisole (766-51-8)

Safety Information

Safety Statements	24/25
WGK Germany	3
TSCA	Yes
HS Code	29093090

MSDS Information

Provider	Language
1-Chloro-2-methoxybenzene	English
ACROS	English
SigmaAldrich	English
ALFA	English

2-Chloroanisole Usage And Synthesis

Chemical Properties	CLEAR LIGHT YELLOW LIQUID
Uses	2-Chloroanisole was used in headspace solid-phase microextraction method for the determination of haloanisoles in wine and spirit samples.
Synthesis Reference(s)	Journal of the American Chemical Society, 96, p. 2252, 1974 DOI: 10.1021/ja00814a045The Journal of Organic Chemistry, 41, p. 732, 1976 DOI: 10.1021/jo00866a043
General Description	2-Chloroanisole undergoes acetylation with acetic anhydride over large pore zeolites to give 4-acetyl-2-chloroanisole.

2-Chloroanisole Preparation Products And Raw materials

Raw materials	3-Chloro-4-methoxybenzyl alcohol-->5-Chloro-2-methoxyphenylboronic acid-->2-Methoxyphenylboronic acid
Preparation Products	4-Bromoanisole-->3-Chloroanisole-->3-chloro-4-methoxyphenylacetic acid-->2-(3-METHOXYPHENYL)CYCLOHEXANONE-->methyl 3-chloro-4-hydroxyphenylacetate-->2,2'-DIMETHOXYBIPHENYL-->2-METHOXYBIPHENYL-->2-Methoxyphenylacetonitrile-->1-(3-CHLORO-4-HYDROXYPHENYL)-1-ETHANONE-->2-METHOXYPHENYLBORONIC ACID PINACOL ESTER-->Meptazinol hydrochloride-->(4-CHLORO-3-METHOXYPHENYL)BORONICACID

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