Other grades of this product :
| Dimethylphenylsilane Basic information |
| Dimethylphenylsilane Chemical Properties |
| Melting point | 323-329 °C(lit.) | | Boiling point | 157 °C744 mm Hg(lit.) | | density | 0.889 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.497(lit.) | | Fp | 95 °F | | storage temp. | Inert atmosphere,2-8°C | | solubility | sol common organic solvent such as chloroform, 1,2-
dichloroethane, benzene, ether, acetone, dioxane, THF; insol
H2O. | | form | solid | | color | Colorless to Almost colorless | | Specific Gravity | 0.889 | | Water Solubility | Not miscible in water. | | Hydrolytic Sensitivity | 3: reacts with aqueous base | | BRN | 2204906 | | InChIKey | ZISUALSZTAEPJH-UHFFFAOYSA-N | | CAS DataBase Reference | 766-77-8(CAS DataBase Reference) | | EPA Substance Registry System | Silane, dimethylphenyl- (766-77-8) |
| Hazard Codes | Xi | | Risk Statements | 10-36 | | Safety Statements | 26-36/39-24/25 | | RIDADR | UN 1993 3/PG 3 | | WGK Germany | 1 | | RTECS | AJ4375000 | | TSCA | Yes | | HazardClass | 3 | | PackingGroup | III | | HS Code | 29319090 |
| Dimethylphenylsilane Usage And Synthesis |
| Chemical Properties | Clear colorless liquid | | Physical properties | bp 157 °C/744 mmHg; d 0.889 g cm?3. | | Uses | Diastereoselective Reduction of Carbonyl Compounds.
Hydrosilylation. With a transition metal catalyst, the
hydrosilane adds to carbon–carbon double or triple bonds to
give alkylsilanes or alkenylsilanes.
Hydrosilylating reagent; reductant in combination with acid
or F?). | | Uses | Dimethylphenylsilane is a reagent for enol ether synthesis. It acts as a catalyst. Also used as a precursor in Optical Emission Spectroscopy of Plasma Deposition Processes. It can react with vinylbenzene to produce (b-Phenyl-ethyl)-dimethylphenyl-silan. | | Uses | Reagent for enol ether synthesis. | | Application | Used to reduce α-amino ketones to aminoethanols withhigh stereoselectivity. Used in the fluoride ion-catalyzedreduction of aldehydes and ketones, and α-substitutedalkanones to threo products. Erythro reduction of α-substituted alkanones to diols and aminoethanols. Together with CuCl reduces aryl ketones, but not dialkylketones. Used in the silylformylation of acetylenes.Excellent reducing agent for the reduction of enones tosaturated ketones. Shows better selectivity than LAH inthe reduction of oximes to alkoxyamines. |
| Dimethylphenylsilane Preparation Products And Raw materials |
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