4-Bromophenylacetylene

4-Bromophenylacetylene
  • CAS No.:766-96-1
Other grades of this product :
4-Bromophenylacetylene Basic information
Product Name:4-Bromophenylacetylene
Synonyms:(4-BROMPHENYL)-ACETYLEN 97%;(4-Bromophenyl)acetylene,97%;(4-BroMphenyl)acetylene;4'-BROMOPHENYL ACETYLENE;4-BROMOPHENYLACETYLENE;Benzene, 1-broMo-4-ethynyl-;(4-BroMphenyl)acetylene, 95+%;1-Bromo-4-ethynylbenzene 97%
CAS:766-96-1
MF:C8H5Br
MW:181.03
EINECS:628-102-6
Product Categories:Aromatic Halides (substituted);pharmacetical;Aromatics Compounds;Aromatics;Alkynyl;Halogenated Hydrocarbons;Organic Building Blocks
Mol File:766-96-1.mol
4-Bromophenylacetylene Chemical Properties
Melting point 64-67 °C(lit.)
Boiling point 88-90°C 16mm
density 1.4255 (rough estimate)
refractive index 1.6411 (estimate)
Fp 88-90°C/16mm
storage temp. Sealed in dry,Store in freezer, under -20°C
solubility Soluble in chloroform, diethyl ether and ethanol.
form Powder, Crystalline Powder or Solid
color White to yellow
BRN 1209726
CAS DataBase Reference766-96-1(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-bromo-4-ethynyl-(766-96-1)
Safety Information
Hazard Codes Xn,N
Risk Statements 22-51/53
Safety Statements 61
RIDADR UN 3077 9/PG 3
WGK Germany 2
HazardClass 9
PackingGroup III
HS Code 29039990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
4-Bromophenylacetylene Usage And Synthesis
Chemical PropertiesOff-White Solid
UsesStarting material for heterocyclotriynes, second-order nonlinear optical materials, and unsymmetrical 1,4-diarylbutadiynes
Uses4-Bromophenylacetylene, is used as the starting material for second-order nonlinear optical materials, heterocyclotriynes, and unsymmetrical 1,4-diarylbutadiynes.
Uses1-Bromo-4-ethynylbenzene was used in the synthesis of 1-bromo-4-(4′-tetrahydropyranyloxy-1′-ethynylphenyl)benzene.
Synthesis Reference(s)The Journal of Organic Chemistry, 54, p. 3224, 1989 DOI: 10.1021/jo00274a055Tetrahedron, 62, p. 6673, 2006 DOI: 10.1016/j.tet.2005.12.077

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