4-(TERT-BUTYL)PHENYLACETYLENE
4-(TERT-BUTYL)PHENYLACETYLENE
  • CAS No.:772-38-3
Other grades of this product :
4-(TERT-BUTYL)PHENYLACETYLENE Basic information
Uses
Product Name:4-(TERT-BUTYL)PHENYLACETYLENE
Synonyms:P-T-BUTYLPHENYLACETYLENE;TIMTEC-BB SBB008840;4-(TERT-BUTYL)PHENYLACETYLENE,90+%;4-(TERT-BUTYL)PHENYLACETYLENE;4-(tert-BUTYL)PHENYLACETYLENE 95%;1-(1,1-Dimethylethyl)-4-ethynylbenzene;Benzene, 1-(1,1-diMethylethyl)-4-ethynyl-;1-(tert-Butyl)-4-ethynylbenzene
CAS:772-38-3
MF:C12H14
MW:158.24
EINECS:
Product Categories:Building Blocks;Chemical Synthesis;Alkynes;Organic Building Blocks;Terminal;Organic Building Blocks
Mol File:772-38-3.mol
4-(TERT-BUTYL)PHENYLACETYLENE Chemical Properties
Boiling point 70 °C2 mm Hg(lit.)
density 0.877 g/mL at 25 °C(lit.)
refractive index 1.528-1.53
Fp 180 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Hexanes (Slightly)
form liquid
color Pale green to khaki-brown
Specific Gravity0.889
Water Solubility Difficult to mix with water.
CAS DataBase Reference772-38-3(CAS DataBase Reference)
Safety Information
Hazard Codes N,Xi
Risk Statements 50/53
Safety Statements 36/37-60-61
RIDADR UN 3082 9/PG 3
WGK Germany 3
Hazard Note Irritant
HazardClass 9
HS Code 29029090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
4-(TERT-BUTYL)PHENYLACETYLENE Usage And Synthesis
Uses4-(tert-Butyl)phenylacetylene is a useful research chemical.
Chemical PropertiesClear pale yellowish-brown liquid
Uses4-tert-Butylphenylacetylene is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.
Uses4-tert-Butylphenylacetylene can be used in the synthesis of the following:
  • 1,6-bis(4-tert-butylphenyl)hexa-1,5-diyne-3,4-dione
  • 4,4′,5,5′-tetra(4-tert-butylphenylethynyl)dibenzo-24-crown-8-ether via Sonogashira coupling reaction with 4,4′,5,5′-tetraiododibenzo-24-crown-8-ether
  • 1-(4-tert-butylphenyl)-2-(4-tert-butyldimethylsiloxyphenyl)acetylene via palladium catalyzed coupling with 4-(tert-butyldimethylsiloxy)iodobenzene
General Description4-tert-Butylphenylacetylene can be synthesized from 4-tert-butylstyrene.
4-(TERT-BUTYL)PHENYLACETYLENE Preparation Products And Raw materials
Preparation Products4'-tert-Butylacetophenone-->4-TERT-BUTYLPHENYLACETIC ACID

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