Cupric oxalate

Cupric oxalate
  • CAS No.:814-91-5
Other grades of this product :
Cupric oxalate Basic information
Product Name:Cupric oxalate
Synonyms:Copperoxalatehemihydratebluepowder;Cupric oxalate;Cupric oxalate (1:1);Nsc86015;Kupfer(II)-oxalat;Copper(Ⅱ)oxalate hemihydrate;Copper(II) oxalate hydrate;coppergluconatechelate
CAS:814-91-5
MF:C2CuO4
MW:151.56
EINECS:212-411-4
Product Categories:salt of an organic acid;Organic-metal salt
Mol File:814-91-5.mol
Cupric oxalate Chemical Properties
Melting point anhydrous decomposes at ~300 to copper oxide [HAW93]
storage temp. Refrigerator, under inert atmosphere
solubility Aqueous Base (Slightly)
form Powder
color blue
Water Solubility insoluble
Solubility Product Constant (Ksp)pKsp: 9.35
CAS DataBase Reference814-91-5(CAS DataBase Reference)
EPA Substance Registry SystemCupric oxalate (814-91-5)
Safety Information
Risk Statements 20/21/22
Safety Statements 36
RIDADR UN 2449
HazardClass 6.1(b)
PackingGroup III
Hazardous Substances Data814-91-5(Hazardous Substances Data)
MSDS Information
Cupric oxalate Usage And Synthesis
Chemical PropertiesCupric oxalate is a bluish-white, odorless powder.
UsesAs catalyst for organic reactions; as stabilizer for acetylated polyformaldehyde; in anticaries compositions; in seed treatments to repel birds and rodents.
PreparationCopper(II) oxalate can be prepared by reaction of sodium oxalate with copper(II) salt solutions. Copper(II) oxalate is used as a catalyst in organic reactions and as a stabilizer for acetylated polyformaldehyde.
General DescriptionOdorless bluish-white solid. Denser than water and insoluble in water. Hence sinks in water. Used as a catalysts for organic reactions.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileCupric oxalate dissolves in aqueous ammonia and reacts as an acid to neutralize other bases as well. Can serve as a reducing agent in reactions that generate carbon dioxide.
HazardToxic by ingestion; tissue irritant.
Health HazardInhalation causes irritation of nose and throat. Ingestion of very large amounts may produce symptoms of oxalate poisoning; watch for edema of the glottis and delayed constriction of esophagus. Contact with eyes causes irritation.
Fire HazardSpecial Hazards of Combustion Products: Toxic carbon monoxide gas may form in fire.
Potential ExposureUsed as a catalyst for organic reactions and in seed treatment as a repellent for birds and rodents.
ShippingUN2775, Copper based pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
IncompatibilitiesExplosive materials are formed on contact with acetylene gas, ammonia, caustic solutions; sodium hypobromite, nitromethane. Slight heating can cause a weak explosion. Cupric oxalate dissolves in aqueous ammonia and reacts as an acid to neutralize other bases as well. Can serve as a reducing agent in reactions that generate carbon dioxide. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
Cupric oxalate Preparation Products And Raw materials

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