4'-Chloroacetophenone

4'-Chloroacetophenone
  • CAS No.:99-91-2
Other grades of this product :
4'-Chloroacetophenone Basic information
Product Name:4'-Chloroacetophenone
Synonyms:1-(4-chlorophenyl)-ethanon;Ethanone,1-(4-chlorophenyl)-;ethanone,1-(4-chlorophenyl)-[qr];methyl4-chlorophenylketone;methylp-chlorophenylketone;methylp-chlorophenylketone[qr];p-acetylchlorobenzene;p-chlorophenylmethylketone
CAS:99-91-2
MF:C8H7ClO
MW:154.59
EINECS:202-800-7
Product Categories:C7 to C8;Carbonyl Compounds;FINE Chemical & INTERMEDIATES;Aromatic Acetophenones & Derivatives (substituted);Organics;Ketones;Chlorobenzene Series;Acetophenone Series;99-91-2
Mol File:99-91-2.mol
4'-Chloroacetophenone Chemical Properties
Melting point 14-18 °C (lit.)
Boiling point 232 °C (lit.)
density 1.192 g/mL at 25 °C (lit.)
vapor pressure 8 mm Hg ( 90 °C)
refractive index n20/D 1.554(lit.)
Fp 194 °F
storage temp. Sealed in dry,Room Temperature
solubility 111mg/l (slow decomposition)
form Liquid After Melting
color Clear colorless to yellow
Water Solubility 111 mg/L (25 ºC)
Merck 14,2116
BRN 386014
LogP2.32 at 20℃
CAS DataBase Reference99-91-2(CAS DataBase Reference)
NIST Chemistry ReferenceEthanone, 1-(4-chlorophenyl)-(99-91-2)
EPA Substance Registry System4'-Chloroacetophenone (99-91-2)
Safety Information
Hazard Codes T+,Xn
Risk Statements 22-26-37/38-41-36/37/38-36/37
Safety Statements 26-28-36/37/39-45-28A-36
RIDADR UN 3416 6.1/PG 2
WGK Germany 3
RTECS KM5600000
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29147090
Hazardous Substances Data99-91-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
1-(4-Chlorophenyl)ethanone English
SigmaAldrich English
ACROS English
ALFA English
4'-Chloroacetophenone Usage And Synthesis
Chemical Propertiesclear colourless to yellowish liquid after melting
UsesChloroacetophenone is used as a tear gas for riot control and as a kind of chemical mace against small groups or individuals
Synthesis Reference(s)The Journal of Organic Chemistry, 44, p. 2568, 1979 DOI: 10.1021/jo01328a051Tetrahedron Letters, 42, p. 265, 2001 DOI: 10.1016/S0040-4039(00)01935-3Synthetic Communications, 25, p. 2261, 1995 DOI: 10.1080/00397919508011781
Safety ProfilePoison by intraperitoneal route. Moderately toxic by ingestion. A powerful irritant and lachrymator. Human systemic effects by inhalation: lachrymation and unspecified effects on the eye and sense of smell. Combustible when exposed to heat or flame. To fight fire, use water, foam, alcohol foam, dry chemical. When heated to decomposition or on contact with water or steam it emits toxic fumes of Cl-

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