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| PHENYLMERCURIC CHLORIDE Basic information |
| PHENYLMERCURIC CHLORIDE Chemical Properties |
| Melting point | 248-250 °C (dec.)(lit.) | | storage temp. | Poison room | | form | solid | | Water Solubility | Soluble in benzene, ether, pyridine. Very slightly soluble in water | | Merck | 14,7301 | | BRN | 3536717 | | Exposure limits | ACGIH: TWA 0.1 mg/m3 (Skin)NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3 | | CAS DataBase Reference | 100-56-1(CAS DataBase Reference) | | EPA Substance Registry System | Mercury, chlorophenyl- (100-56-1) |
| PHENYLMERCURIC CHLORIDE Usage And Synthesis |
| Chemical Properties | white fine crystalline powder | | Uses | Phenylmercuric chloride has been used as an agricultural fungicide.
| | Uses | The reaction of phenylmercury (II) chloride with acetophenonethiosemicarbazone (Hatsc) in ethanol in 1: 1 mole ratio undergoes symmetrisation forming the products, HgCl2 (Hatse) 2 and Ph2Hg instead of the anticipated compound PhHgCl (Hatse). A new method for the determination of chloride ion is based on the formation of phenylmercury(II) chloride, its extraction into chloroform and reaction with sodium diethyldithiocarbamate to form phenylmercury(II) diethyldithiocarbamate. | | Safety Profile | Poison by ingestion, intraperitoneal, and subcutaneous routes. Human mutation data reported. When heated to decomposition ir emits very toxic fumes of Cland Hg. See also MERCURY COMPOUNDS and CHLORIDES. |
| PHENYLMERCURIC CHLORIDE Preparation Products And Raw materials |
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