Product

Triethyl 2-fluoro-2-phosphonoacetate

CAS No.：2356-16-3

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Triethyl 2-fluoro-2-phosphonoacetate Basic information

Product Name:	Triethyl 2-fluoro-2-phosphonoacetate
Synonyms:	2-FLUORO-2-PHOSPHONOACETIC ACID TRIETHYL ESTER 95+%;RIETHYL2-FLUORO-2-PHOSPHONOACETATE;2-Fluoro-2-(diethoxyphosphinyl)acetic acid ethyl ester;Fluoro(diethoxyphosphinyl)acetic acid ethyl ester;Diethyl [(ethoxycarbonyl)fluoromethyl]phosphonate 96%;Ethyl (diethoxyphosphonyl)(fluoro)acetate, 2-Fluoro-2-phosphonoacetic acid triethyl ester;(Diethoxyphosphinyl)fluoroacetic Acid Ethyl Ester Ethyl (Diethoxyphosphinyl)fluoroacetate 2-Fluoro-2-phosphonoacetic Acid Triethyl Ester;ethyl 2-(diethoxyphosphoryl)-2-fluoroacetate
CAS:	2356-16-3
MF:	C8H16FO5P
MW:	242.18
EINECS:	627-648-2
Product Categories:	Phosphorus compounds;Fluorinated Building Blocks;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds;Horner-Emmons Reaction;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
Mol File:	2356-16-3.mol

Triethyl 2-fluoro-2-phosphonoacetate Chemical Properties

Boiling point	75 °C0.01 mm Hg(lit.)
density	1.194 g/mL at 25 °C(lit.)
refractive index	n20/D 1.425(lit.)
Fp	165 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
form	clear liquid
Specific Gravity	1.194
color	Colorless to Almost colorless
BRN	1912161
CAS DataBase Reference	2356-16-3(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi,F
Risk Statements	36/37/38
Safety Statements	26-36-37/39
WGK Germany	3
F	10-21
Hazard Note	Irritant
HazardClass	IRRITANT, FLAMMABLE
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

Triethyl 2-fluoro-2-phosphonoacetate Usage And Synthesis

Chemical Properties	clear colorless liquid
Uses	Reactant for: Diels-Alder reactions Biosynthesis of terpene Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates Synthesis of quinolones Horner-Wadsworth-Emmons asymmetric hydration Addition reactions and the subsequent application to click chemistry Asymmetric intermolecular Stetter reactions
Synthesis Reference(s)	The Journal of Organic Chemistry, 60, p. 4730, 1995 DOI: 10.1021/jo00120a014

Triethyl 2-fluoro-2-phosphonoacetate Preparation Products And Raw materials

Raw materials

DIETHYL (DIBROMOFLUOROMETHYL)PHOSPHONATE, 98-->Ethyl bromofluoroacetate-->ETHYL IODOFLUOROACETATE

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