| DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Basic information |
| Product Name: | DIMETHYLAMINOPYRIDINE, POLYMER-BOUND |
| Synonyms: | POLYMER SUPPORTED DIMETHYLAMINOPYRIDINE;PL-DMAP RESIN;N-METHYL-N-(4-PYRIDYL)AMINOMETHYL-POLYSTYRENE CROSSLINKED WITH DIVINYLBENZENE;N-BENZYLMETHYLAMINOPYRIDINE POLYMER BOUND;DIMETHYLAMINOPYRIDINE ON POLYSTYRENE;DIMETHYLAMINOPYRIDINE, POLYMER-BOUND;4-(Dimethylamino)pyridine, polymer-bound 200-400 mesh, extent of labeling: ~6.0 mmol/g loading, 2 % cross-linked;loading, matrix crosslinked with 2% DVB |
| CAS: | 82942-26-5 |
| MF: | C8H8 |
| MW: | 0 |
| EINECS: | |
| Product Categories: | BasesChemical Synthesis;Organic Bases;Supported Reagents;Supported Synthesis;Synthetic Reagents |
| Mol File: | Mol File |
| DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Chemical Properties |
| Fp | 4 °C |
| Safety Information |
| Hazard Codes | Xi,T |
| Risk Statements | 36/37/38-23/24/25 |
| Safety Statements | 26-37/39-45-36/37/39-28-16 |
| RIDADR | UN 3175 4.1/PG 2 |
| WGK Germany | 3 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Usage And Synthesis |
| Uses | Polymer-bound 4-(dimethylamino)pyridine is used as a supported base in the Michael addition and nitrous acid elimination process step involved in the synthesis of thiophene-2-carboxylates using β-nitroacrylates as starting materials, under a general and efficient continuous flow-based protocol. It also serves as a supported catalyst in the preparation of ω-nitro esters starting from cyclic 2-nitro ketones under solid heterogeneous catalysis.(5) |
| General Description | Polymer-bound 4-(dimethylamino)pyridine is used for improved derivatization of chiral and achiral aliphatic amines, amino alcohols and amino acids. |
| DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Preparation Products And Raw materials |
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