Methyl 3-bromopropionate

CAS No.：3395-91-3

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This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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Methyl 3-bromopropionate Basic information

Product Name:	Methyl 3-bromopropionate
Synonyms:	3-bromopropanoicacidmethylester;3-bromo-propanoicacimethylester;3-bromo-propionicacimethylester;Methyl 3-bromopropanoate;methyl3-bromopropanoate;Propionic acid, 3-bromo-, methyl ester;METHYL 3-BROMOPROPIONATE;METHYL BETA-BROMOPROPIONATE
CAS:	3395-91-3
MF:	C4H7BrO2
MW:	167
EINECS:	222-247-5
Product Categories:	Building Blocks;C2 to C5;Organics;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;C2 to C5;Carbonyl Compounds;Esters;bc0001
Mol File:	3395-91-3.mol

Methyl 3-bromopropionate Chemical Properties

Melting point	75°C
Boiling point	64-66 °C/18 mmHg (lit.)
density	1.53 g/mL at 25 °C (lit.)
refractive index	n20/D 1.458(lit.)
Fp	167 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	Liquid
color	Clear colorless to slightly yellow
Water Solubility	Immiscible
BRN	1742949
CAS DataBase Reference	3395-91-3(CAS DataBase Reference)
NIST Chemistry Reference	Propanoic acid, 3-bromo-, methyl ester(3395-91-3)
EPA Substance Registry System	Propanoic acid, 3-bromo-, methyl ester (3395-91-3)

Safety Information

Hazard Codes	Xn
Risk Statements	22-36/37/38
Safety Statements	26-37/39-24/25
WGK Germany	3
RTECS	UA2451790
TSCA	Yes
HS Code	29159080

MSDS Information

Provider	Language
Methyl 3-bromopropionate	English
SigmaAldrich	English
ACROS	English
ALFA	English

Methyl 3-bromopropionate Usage And Synthesis

Chemical Properties	Very slightly yellow liquid
Uses	Methyl 3-bromopropionate was used in the synthesis of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-l-oxaspiro[n,m]alkan-2-ones.

Methyl 3-bromopropionate Preparation Products And Raw materials

Raw materials	1-Bromo-2-methoxyethane-->Methyl 3-methoxypropionate
Preparation Products	Methyl 3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl) propionate-->METHYL 4-NITROBUTYRATE-->4-BroMo-2-Methylbutan-2-ol-->METHYL 4-ACETYL-5-OXOHEXANOATE

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