2-(Trimethylsiloxy)-1,3-butadiene

2-(Trimethylsiloxy)-1,3-butadiene
  • CAS No.:38053-91-7
Other grades of this product :
2-(Trimethylsiloxy)-1,3-butadiene Basic information
Product Name:2-(Trimethylsiloxy)-1,3-butadiene
Synonyms:2-(TRIMETHYLSILOXY)-1,3-BUTADIENE;2-TRIMETHYLSILYLOXY-1,3-BUTADIENE;Trimethylsiloxybutadiene;Silane, trimethyl(1-methylene-2-propenyl)oxy-;2-(TRIMETHYLSILOXY)-1,3-BUTADIENE 98+%;2-(TRIMETHYLSILOXY)-1,3-BUTADIENE FOR SY;(1-Methyleneallyloxy)trimethylsilane;1,3-Butadiene-2-yloxytrimethylsilane
CAS:38053-91-7
MF:C7H14OSi
MW:142.27
EINECS:
Product Categories:Monoalkoxysilanes;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Si-O Compounds;Synthetic Organic Chemistry;Vinylsilanes, Allylsilanes
Mol File:38053-91-7.mol
2-(Trimethylsiloxy)-1,3-butadiene Chemical Properties
Melting point <0°C
Boiling point 50 °C
density 0.807
refractive index 1.4480
Fp 12°C
storage temp. Store at +2°C to +8°C.
solubility sol most standard organic solvents.
form clear liquid
color Colorless to Light yellow to Light orange
Specific Gravity0.807
Hydrolytic Sensitivity7: reacts slowly with moisture/water
CAS DataBase Reference38053-91-7(CAS DataBase Reference)
Safety Information
Risk Statements 11-23/24/25
Safety Statements 16-23-36/37/39-45
RIDADR 1992
WGK Germany WGK 3 highly water endangering
Autoignition Temperature350 °C
TSCA No
HS Code 2931 90 00
HazardClass 3
PackingGroup II
MSDS Information
2-(Trimethylsiloxy)-1,3-butadiene Usage And Synthesis
Physical propertiesbp 50–55 °C/50 mmHg; d 0.811 g cm?3.
Uses2-Trimethylsilyloxy-1,3-butadiene is easily prepared reactive diene for Diels–Alder reactions and other cycloadditions; reactive silyl enol ether for aldol,Michael reactions, and electrophilic additions. It participates in the reactions of Diels–Alder Reactions, Heterodienophiles, [2 + 2] and Other Cycloadditions, Carbene Additions, Aldol Condensations and Electrophilic Additions.
Preparation2-Trimethylsilyloxy-1,3-butadiene can be prepared easily from methyl vinyl ketone.

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