Bismuth(III) trifluoromethanesulfonate

CAS No.：88189-03-1

Other grades of this product :

Bismuth(III) trifluoromethanesulfonate Basic information

Uses

Product Name:	Bismuth(III) trifluoromethanesulfonate
Synonyms:	BISMUTH(III)TRIFLATE;BISMUTH(III) TRIFLUOROMETHANESULFONATE;BISMUTH(III)TRIFLUOROMETHANESULPHONATE;BISMUTH TRIFLATE;BISMUTH TRIFLUOROMETHANESULFONATE HYDRATE;BISMUTH TRIFLUOROMETHANESULFONATE, ANHY&;Trifluoromethanesulfonicacidbismuthsalt;Bismuth(III)trifluoromethanesulfonate,min.98%(Bismuthtriflate)
CAS:	88189-03-1
MF:	3CF3O3S.Bi
MW:	656.18
EINECS:
Product Categories:	metal triflate compound;triflate;Bismuth;Catalysis and Inorganic Chemistry;Chemical Synthesis
Mol File:	88189-03-1.mol

Bismuth(III) trifluoromethanesulfonate Chemical Properties

Melting point	300 °C
storage temp.	Inert atmosphere,Room Temperature
solubility	Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.
form	Liquid
color	Clear colorless
Sensitive	Hygroscopic
Hydrolytic Sensitivity	5: forms reversible hydrate
Stability:	hygroscopic
InChIKey	HIYUMYXSGIKHHE-UHFFFAOYSA-M

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-24/25
WGK Germany	3
Hazard Note	Irritant
TSCA	No
HazardClass	8
HS Code	29049090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

Bismuth(III) trifluoromethanesulfonate Usage And Synthesis

Uses	Bismuth(III) trifluoromethanesulfonate is powerful Lewis acid useful in a number of catalytic reactions.
Chemical Properties	White powder
Uses	Catalyst for organic syntheses.
Uses	Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
Uses	Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.

Bismuth(III) trifluoromethanesulfonate Preparation Products And Raw materials

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