Anthrone

CAS No.：90-44-8

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Anthrone Basic information

Product Name:	Anthrone
Synonyms:	(10H)-9-Anthracenone;Anthrone test solution(ChP);2H-anthracen-1-one;9-oxoanthracene;Anthracene, 9,10-dihydro-9-oxo-;Anthranone;9,10-dihydro-9-oxo-anthracen;CARBOTHRONE
CAS:	90-44-8
MF:	C14H10O
MW:	194.23
EINECS:	201-994-0
Product Categories:	A;A to Z;Building Blocks;C13 to C14;Carbonyl Compounds;Chemical Synthesis;Industrial/Fine Chemicals;Dyes;Hematology and Histology;Ketones;Organic Building Blocks;Stains &Stains and Dyes;Pyridines;Intermediates
Mol File:	90-44-8.mol

Anthrone Chemical Properties

Melting point	154-157 °C (lit.)
Boiling point	721 °C
density	1.0550 (rough estimate)
refractive index	1.5500 (estimate)
storage temp.	2-8°C
solubility	INSOLUBLE
form	Powder
color	Yellow
Water Solubility	INSOLUBLE
Sensitive	Light Sensitive
Merck	14,691
BRN	1910173
Stability:	Stable. Incompatible with strong oxidizing agents. Combustible.
InChIKey	RJGDLRCDCYRQOQ-UHFFFAOYSA-N
CAS DataBase Reference	90-44-8(CAS DataBase Reference)
NIST Chemistry Reference	Anthrone(90-44-8)
EPA Substance Registry System	9(10H)-Anthracenone (90-44-8)

Safety Information

Hazard Codes	Xi,Xn
Risk Statements	36/37/38-20/21/22
Safety Statements	26-36
WGK Germany	3
RTECS	CB8925500
F	8
TSCA	Yes
HS Code	29143990
Hazardous Substances Data	90-44-8(Hazardous Substances Data)
Toxicity	mmo-sat 60 mg/plate MUREAV 157,149,85

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

Anthrone Usage And Synthesis

Chemical Properties	off-white to light yellow crystals
Uses	Anthrone is a tricyclic aromatic ketone and related compound of anthracene. Anthrone is used as a reagent in the colorometric determination of carbohydrates.
Uses	Used for determination of carbohydrates Anthrone is used for the determination of carbohydrates. It is used as a general reagent in the colorimetric determination of carbohydrates in yeast and plant extracts. It is involved in organic synthesis. It is utilized for the determination of sugar in body fluids. It finds application as a laxative.
Definition	ChEBI: A member of the class of anthracenes that is 9,10-dihydroanthracene carrying an oxo group at C-9.
General Description	Anthrone has the ability to reduce aldehyde containing reducing sugars such as streptose and N-acetyl glucosamine present in streptomycin, into acids. It develops a red- violet color. Therefore, it is used to determine streptomycin quantitatively. Anthrone has been used to detect carbohydrate containing lipids and to measure sugar content such as sucrose and trehalose in the liquid medium.
Safety Profile	Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.
Purification Methods	This stable keto tautomer of 9-anthranol (above) provides yellow crystals from a 3:1 mixture of C6H6/pet ether (b 60-80o) (10-12mL/g), or successively from C6H6 then EtOH. Dry it in vacuo. [Meyer Org Synth Coll Vol I 60 1941, Beilstein 6 IV 4930.]

Anthrone Preparation Products And Raw materials

Raw materials	Anthraquinone-->Tin granular-->Acetic acid 9-anthryl ester-->9(10H)-Anthracenone, oxime-->9,10-DIHYDROANTHRACEN-9-OL-->9,10-Dihydroxy-9,10-dihydroanthracene-->2-BENZYLBENZOIC ACID-->tert-Butyl peroxybenzoate
Preparation Products	9-VINYLANTHRACENE-->Benzanthrone-->10-Nitroanthrone-->Solvent Red 52-->9-phenylanthracene-->Solvent Red 149-->Vat Black 29-->9,10-DIHYDROANTHRACENE-->Anthracene-->oxanthranol-->9-Bromo-10-(2-naphthyl)anthracene-->Bianthrone

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