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| 2,7-Dibromofluorene Basic information |
| Product Name: | 2,7-Dibromofluorene | | Synonyms: | 2,7-DIBROMOFLUORENE;Aluminum oxide, fused, #325 mesh, 99+%;Dibromofluorene;TIMTEC-BB SBB007691;2,7-Dibromofluorene, 98+%;2,7-Dibromo-9H-fluorene;Fluorene, 2,7-dibromo-;2,7-Dibromofluorene,99% | | CAS: | 16433-88-8 | | MF: | C13H8Br2 | | MW: | 324.01 | | EINECS: | 629-430-2 | | Product Categories: | Thiadiazoles ,Benzothiazoles;OLED materials,pharm chemical,electronic;blocks;Bromides;Halogenated Hydrocarbons;Fluorene Series;Fluorene Derivatives;Fluorenes, Flurenones;Fluorenes;Fluorenes & Fluorenones;Aryl;C13 to C37+ | | Mol File: | 16433-88-8.mol |
| 2,7-Dibromofluorene Chemical Properties |
| Melting point | 164-166 °C (lit.) | | Boiling point | 329.77°C (rough estimate) | | density | 1.7203 (estimate) | | refractive index | 1.6000 (estimate) | | storage temp. | Sealed in dry,Room Temperature | | solubility | Chloroform (Slightly) | | form | Crystalline Powder | | color | White to off-white | | BRN | 2049205 | | InChIKey | AVXFJPFSWLMKSG-UHFFFAOYSA-N | | CAS DataBase Reference | 16433-88-8(CAS DataBase Reference) | | NIST Chemistry Reference | 9H-fluorene, 2,7-dibromo-(16433-88-8) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | TSCA | T | | HazardClass | IRRITANT | | HS Code | 29420000 |
| 2,7-Dibromofluorene Usage And Synthesis |
| Description | 2,7-Dibromofluorene is a halogenated polycyclic aromatic compound and its vapour pressure has been measured using the Knudsen effusion method. | | Chemical Properties | white to off-white crystalline powder | | Uses | 2,7-Dibromofluorene was used as a template for the N-carbazole capped oligofluorenes which show potential as hole-transporting materials for organic light emitting devices (OLEDs). It may be used in the synthesis of conjugated polymer, poly[9,9′-bis(6′′-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), used in label-free DNA microarrays. It was used in the preparartion of blue photoluminescent unsymmetrically substituted polyfluorene. It was also used in the preparation of 2,7-dibromofluorene monomers containing benzyl ether dendrons (generations 1, 2 and 3) in the 9,9′-position of the fluorene ring, such as:9,9-bis[(3,5-bis(benzyloxy)benzyloxy)methyl]-2,7-dibromofluorene9,9-bis[(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy)-methyl] 2,7-dibromo-fluorene9,9-bis[(3,5-bis(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy) benzyloxy)-methyl]-2,7-dibromofluorene | | Uses | 2,7-Dibromofluorene is used as a template for the N-carbazole capped oligofluorenes which show potential as hole-transporting materials for organic light emitting devices (OLEDs). It is also used in the synthesis of conjugated polymer, poly[9,9?-bis(6??-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), used in label-free DNA microarrays, in the preparation of blue photoluminescent unsymmetrically substituted polyfluorene and in the preparation of 2,7-dibromofluorene monomers containing benzyl ether dendrons (generations 1, 2 and 3) in the 9,9?-position of the fluorene ring, such as: 9,9-bis[(3,5-bis(benzyloxy)benzyloxy)methyl]-2,7-dibromofluorene, 9,9-bis[(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy)-methyl] 2,7-dibromo-fluorene, 9,9-bis[(3,5-bis(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy) benzyloxy)-methyl]-2,7-dibromofluorene. | | Uses | 2,7-Dibromofluorene was used as a template for the N-carbazole capped oligofluorenes which show potential as hole-transporting materials for organic light emitting devices (OLEDs). It may be used in the synthesis of conjugated polymer, poly[9,9′-bis(6′′-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), used in label-free DNA microarrays. It was used in the preparartion of blue photoluminescent unsymmetrically substituted polyfluorene. It was also used in the preparation of 2,7-dibromofluorene monomers containing benzyl ether dendrons (generations 1, 2 and 3) in the 9,9′-position of the fluorene ring, such as:- 9,9-bis[(3,5-bis(benzyloxy)benzyloxy)methyl]-2,7-dibromofluorene
- 9,9-bis[(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy)-methyl] 2,7-dibromo-fluorene
- 9,9-bis[(3,5-bis(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy) benzyloxy)-methyl]-2,7-dibromofluorene
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| 2,7-Dibromofluorene Preparation Products And Raw materials |
| Preparation Products | 2,7-Dibromo-9H-fluoren-9-one-->2,7-Dibromo-9,9'-spiro-bifluorene-->2,7-Dibromo-9,9-dimethylfluorene-->3,3'-(2,7-DibroMo-9H-fluorene-9,9-diyl)bis(N,N-diMethylpropan- 1-aMine)-->(2,7-BIS(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-9,9-DIOCTYLFLUORENE) |
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