TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE

TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
  • CAS No.:85417-41-0
Other grades of this product :
TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Basic information
Product Name:TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
Synonyms:TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE;TDMPP;Tris(2,6-dimethoxyphenly)phosphine;TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE 97+% HPLC;Tris(2,6-dimethoxyphenyl)phosphine, 97+%;Tris(2,6-diMethoxyphenyl)phosphine, 97+% 5GR;Tris(2,6-dimethoxyphenyl)phosphine 98%;Tris(2,6-dimethoxyphenyl)phosphine, min. 97%
CAS:85417-41-0
MF:C24H27O6P
MW:442.44
EINECS:
Product Categories:Ligand;Phosphine Ligands;Synthetic Organic Chemistry;Basic Phosphine LigandsCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;Cross-Coupling;Phosphine Ligands;Phosphorus Compounds
Mol File:85417-41-0.mol
TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Chemical Properties
Melting point 145-147 °C(lit.)
Boiling point 566.4±50.0 °C(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility very faint turbidity in hot Methanol
form Powder
color white to off-white
Sensitive air sensitive
CAS DataBase Reference85417-41-0
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
TSCA No
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesCatalyst for:
  • Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
  • Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
  • Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
  • Oxycylizations of allendiols
  • Enantioselective aldol reactions
  • Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions
TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Preparation Products And Raw materials

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