Product

1,1'-FERROCENEDICARBOXYLIC ACID

CAS No.：1293-87-4

Other grades of this product :

1,1'-FERROCENEDICARBOXYLIC ACID Basic information

Product Name:	1,1'-FERROCENEDICARBOXYLIC ACID
Synonyms:	1,1'-FERROCENEDICARBOXYLIC ACID;1,1'-DICARBOXYFERROCENE;1,1-Ferrocnedocarboxylic Acid;1,1-Ferrpemedocarboxylic Acid;FERROCENE-1,1'-DICARBOXYLIC ACID;BIS(CARBOXYCYCLOPENTADIENYL)IRON;Ferrocene dicarboxylic acid;Ferrocene, 1,1'-dicarboxy-
CAS:	1293-87-4
MF:	C12H10FeO410*
MW:	274.05
EINECS:	215-068-9
Product Categories:	Classes of Metal Compounds;Fe (Iron) Compounds;Miscellaneous;Ferrocenes;Metallocenes;Transition Metal Compounds;Industrial/Fine Chemicals;Catalysis and Inorganic Chemistry;Chemical Synthesis
Mol File:	1293-87-4.mol

1,1'-FERROCENEDICARBOXYLIC ACID Chemical Properties

Melting point	≥300 °C(lit.)
storage temp.	Inert atmosphere,Room Temperature
solubility	DMSO, Ethyl Acetate (Very Slightly, Heated, Sonicated)
form	crystal
color	orange
Water Solubility	Insoluble
Exposure limits	ACGIH: TWA 1 mg/m3NIOSH: TWA 1 mg/m3
Stability:	Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference	1293-87-4
NIST Chemistry Reference	1,1'-Ferrocenedicarboxylic acid(1293-87-4)

Safety Information

Hazard Codes	Xi,Xn
Risk Statements	36/37/38-22
Safety Statements	26-36-37/39
WGK Germany	3
HS Code	29319090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

1,1'-FERROCENEDICARBOXYLIC ACID Usage And Synthesis

Chemical Properties	dark brown powder
Uses	Reactant for preparation of: Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions Potential antitumor agents Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties Prganometallic aromatic polyesters Manganese-lanthanide-ferrocene clusters
Purification Methods	It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.]

1,1'-FERROCENEDICARBOXYLIC ACID Preparation Products And Raw materials

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