3-Methyl-3-oxetanemethanol

3-Methyl-3-oxetanemethanol
  • CAS No.:3143-02-0
Other grades of this product :
3-Methyl-3-oxetanemethanol Basic information
Product Name:3-Methyl-3-oxetanemethanol
Synonyms:3-METHYL-3-OXETANEMETHANOL;3-METHYL-3-OXETHANEMETHANOL;3-HYDROXYMETHYL-3-METHYLOXETANE;3-Methyl-3-(hydroxymethyl)oxetane;3-METHYL-3-OXETANEMETHANOL, 98+%;2-HYDROXYMETHYL-2-METHYL-1,3-EPOXYPROPANE;RARECHEM AK ML 0581;TIMTEC-BB SBB009078
CAS:3143-02-0
MF:C5H10O2
MW:102.13
EINECS:684-156-0
Product Categories:Oxetanes;Simple 4-Membered Ring Compounds;Thiophenes;3143-02-0
Mol File:3143-02-0.mol
3-Methyl-3-oxetanemethanol Chemical Properties
Boiling point 80 °C/40 mmHg (lit.)
density 1.024 g/mL at 25 °C (lit.)
refractive index n20/D 1.446(lit.)
Fp 210 °F
storage temp. 2-8°C
solubility Soluble in chloroform, methanol.
form Liquid
pka14.58±0.10(Predicted)
Specific Gravity1.024
color Clear colorless to pale yellow
BRN 102773
InChIKeyNLQMSBJFLQPLIJ-UHFFFAOYSA-N
CAS DataBase Reference3143-02-0(CAS DataBase Reference)
NIST Chemistry Reference3-Methyl-3-oxetanemethanol(3143-02-0)
Safety Information
Hazard Codes Xi
Risk Statements 43
Safety Statements 23-24/25-36/37
WGK Germany 3
HS Code 29329990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
3-Methyl-3-oxetanemethanol Usage And Synthesis
Chemical PropertiesClear colorless to pale yellow liquid
Uses3-Methyl-3-oxetanemethanol has been used in the preparation of star-shaped copolymer consisting of a hyperbranched poly(3-methyl-3-oxetanemethanol) core and polytetrahydrofuran arms, pyridyl disulfide-functionalized cyclic carbonate monomer, required for the synthesis of of functional poly(ε-caprolactone) containing pendant pyridyl disulphide groups and δ-lactams. It is used to synthesize octahydroindole alkaloids and γ-butenolides.
Synthesis Reference(s)Tetrahedron Letters, 24, p. 5571, 1983 DOI: 10.1016/S0040-4039(00)94143-1
Purification MethodsPurify the oxetane by fractionation through a glass column [Pattison J Am Chem Soc 79 3455 1957, Corey et al. J Am Chem Soc 106 2736 1984]. [Beilstein 17 III/IV 1128.]
3-Methyl-3-oxetanemethanol Preparation Products And Raw materials
Raw materials3-Oxetanemethanol, 3-methyl-, nitrate-->1,1,1-Tris(hydroxymethyl)ethane-->Ethyl nitrate

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