(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE

(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE
  • CAS No.:127184-05-8
Other grades of this product :
(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE Basic information
Product Name:(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE
Synonyms:(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE;(+)-3,3-DICHLORO-2,N-EPOXY-EXO-10,2-BORNANESULTAM;4H-4a,7-Methanooxazirino3,2-i2,1benzisothiazole, 8,8-dichlorotetrahydro-9,9-dimethyl-, 3,3-dioxide, (2R,4aS,7S,8aR)-;(+)-[(8,8-DICHLOROCAMPHORYL)-SULFONYL]-OXAZIRIDINE 97+%;[2R-(2α,4aα,7α,8aR*)]-8,8-Dichlorotetrahydro-9,9-diMethyl-4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-Dioxide;(+)-(8,8-DichlorocaMphorylsulfonyl)oxaziridine >=97.0% (T);(4aS,7S,8aR)-8,8-dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide;(1S,6R,8S)-7,7-dichloro-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.01,?.0?,?]undecane-3,3-dione
CAS:127184-05-8
MF:C10H13Cl2NO3S
MW:298.19
EINECS:
Product Categories:Heterocycles;Miscellaneous Reagents
Mol File:127184-05-8.mol
(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE Chemical Properties
Melting point 181-186 °C
Boiling point 390.5±52.0 °C(Predicted)
density 1.68±0.1 g/cm3(Predicted)
storage temp. 2-8°C
solubility Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form Solid
pka-15.63±0.60(Predicted)
color White to Off-White
optical activity[α]20/D +89±3°, c = 0.5% in chloroform
BRN 3653352
Safety Information
Safety Statements 22-24/25
RIDADR 1479
WGK Germany 3
8-10
HazardClass 5.1
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE Usage And Synthesis
Chemical PropertiesWhite Solid
UsesChiral oxidizing agent.
UsesOxidizing reagent.
Purification MethodsRecrystallise the enantiomers from EtOH [Davis & Weismiller J Org Chem 55 3715 1990].
(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE Preparation Products And Raw materials
Raw materials(3aS,6S)-7,7-Dichloro-4,5,6,7-tetrahydro-8,8-diMethyl-3H-3a,6-Methano-2,1-benzisothiazole 2,2-Dioxide-->(1S)-(-)-CAMPHORSULFONYLIMINE

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