ALPHA-D-GALACTURONIC ACID HYDRATE

ALPHA-D-GALACTURONIC ACID HYDRATE
  • CAS No.:91510-62-2
Other grades of this product :
ALPHA-D-GALACTURONIC ACID HYDRATE Basic information
Product Name:ALPHA-D-GALACTURONIC ACID HYDRATE
Synonyms:ALPHA-D-GALACTURONIC;alpha-D-Galacturonic Acid D(+)-Galacturonic acid monohydrate,99%;D-Galacturonic acid hydrate;D-(+)-Galacturonic acid Monohydrat;D-Galacturonic acid Monohyarate;D-(+)-Galacturonic acid Monohydrate >=97.0%;(2S,3R,4S,5R)
CAS:91510-62-2
MF:C6H12O8
MW:212.15
EINECS:211-682-6
Product Categories:Carbohydrates & Derivatives;Sugar Acids;Sugars;Carbohydrate Synthesis;Monosaccharides;Specialty Synthesis;Biochemistry;Galactose
Mol File:91510-62-2.mol
ALPHA-D-GALACTURONIC ACID HYDRATE Chemical Properties
Melting point 156-159℃
alpha +51.7°(23℃/D, c=1, H2O)
refractive index 52.5 ° (C=10, H2O)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly, Sonicated), Methanol (Slightly), Water (Slightly)
form Powder
color White to Off-white
optical activity[α]20/D +53±2°, 5 hr, c = 10% in H2O
Water Solubility Soluble in water
Merck 14,4337
BRN 1727087
CAS DataBase Reference91510-62-2(CAS DataBase Reference)
Safety Information
Safety Statements 24/25
WGK Germany 3
TSCA Yes
HS Code 29329990
MSDS Information
ALPHA-D-GALACTURONIC ACID HYDRATE Usage And Synthesis
Chemical Propertieswhite to light beige fine powder
UsesALPHA-D-GALACTURONIC ACID HYDRATE is highly purified product form Pectine.It is used in the synthesis of N-(D-galacturonoyl) amino acids and dipeptides.
UsesHighly purified product form Pectine.
UsesD-(+)-Galacturonic acid monohydrate is a chemical used in the synthesis of N-(D-galacturonoyl) amino acids and dipeptides.
Purification MethodsCrystallisation of the acid from 95% EtOH and drying it in a vacuum desiccator (12mm) over P2O5 gives the monohydrate mixture of and anomers (mostly -) as white micro needles, which sinter at ~100-111o and melt at 159-160o, [] D 20 +107o (initial, c 4 in H2O mutarotating to +51o). [Link & Sell Biochemical Preparations 3 74, 78 1953, Beilstein 3 IV 2000.] The -anomer is obtained by warming the -anomer in EtOH, AcOH or EtOAc and has m 1 6 0o (165o, sinters at 1 4 0o), [] D 20 +27o (initial, c 2 in H2O mutarotating to +55.3o in 24hours). The sodium salt [14984-39-5] M 216.1 has [] D 20 +27o (c 10 in H2O after 5hours). The phenylhydrazone has m 141o(from MeOH). [Ehrlich & Schubert Chem Ber 62 1974, 2014 1929, Anderson & King J Chem Soc 5333 1961, Beilstein 3 IV 2001.]
ALPHA-D-GALACTURONIC ACID HYDRATE Preparation Products And Raw materials

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