Rhodium carbonyl chloride

Rhodium carbonyl chloride
  • CAS No.:14523-22-9
Other grades of this product :
Rhodium carbonyl chloride Basic information
Reaction
Product Name:Rhodium carbonyl chloride
Synonyms:Dirhodium tetracarbonyl dichloride;Di-μ-chloro-tetracarbonyldirhodium(I), Rhodium carbonyl chloride(I), Rhodium(I) carbonyl chloride, Rhodium(I) dicarbonyl chloride dimer, Tetracarbonyldi-μ-chlorodirhodium(I);Rhodium carbonyl chloride(I), Rhodium(I) carbonyl chloride, Rhodium(I) dicarbonyl chloride dimer, Tetracarbonyldi-μ-chlorodirhodium(I);Tetracarbonyldi--chlorodirhodium(I);TETRACARBONYLDI-MU-CHLORODIRHODIUM(I);TETRACARBONYLDI-U-CHLORODIRHODIUM(I);BIS(CHLORODICARBONYL)RHODIUM;DI-MU-CHLORO-TETRACARBONYLDIRHODIUM
CAS:14523-22-9
MF:4CO.Cl2Rh2
MW:388.77
EINECS:238-540-6
Product Categories:metal carbonyl complexes;Rh;Metal Compounds
Mol File:14523-22-9.mol
Rhodium carbonyl chloride Chemical Properties
Melting point 120-125 °C (dec.)(lit.)
storage temp. 2-8°C
solubility It is soluble in organic or non-aqueous solvent.
form crystal
color red
Water Solubility soluble in most organic solvents; insoluble aliphatic hydrocarbons [MER06]
Sensitive Air & Moisture Sensitive
Merck 14,8187
Exposure limitsACGIH: TWA 1 mg/m3NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference14523-22-9(CAS DataBase Reference)
NIST Chemistry ReferenceDirhodium tetracarbonyl dichloride(14523-22-9)
Safety Information
Hazard Codes T
Risk Statements 36/38-25
Safety Statements 22-24/25-37/39-28A-26-15
RIDADR UN3466
WGK Germany 3
10-21-23
TSCA No
HazardClass 6.1
PackingGroup III
HS Code 28439000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Rhodium carbonyl chloride Usage And Synthesis
ReactionCatalyst used for a wide range of cycloadditions reactions.
Chemical Propertiesred to brownish crystals, crystalline powder or
UsesCatalyst for organic reactions.
UsesRhodium Carbonyl Chloride is a reagent for rhodium-catalyzed [4+2+1] cycloaddition of in situ generated ene/yne-ene-allenes and carbon monoxide to produce [4+2+1] cycloadducts
Rhodium carbonyl chloride Preparation Products And Raw materials

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