D(-)-Arabinose

D(-)-Arabinose
  • CAS No.:28697-53-2
Other grades of this product :
D(-)-Arabinose Basic information
Product Name:D(-)-Arabinose
Synonyms:D(-)-Arabinose, p.a.;D-Arabinpyranose, 99%;D-ARA;(3S,4R,5R)-OXANE-2,3,4,5-TETROL;D(-)-ARABINOSE MOLECULAR BIOLOGYREAGENT;D-(-)-ARABINOSE SIGMAULTRA;D-Arabinopyranose (9CI);biotechgrade
CAS:28697-53-2
MF:C5H10O5
MW:150.13
EINECS:233-708-5
Product Categories:Carbohydrates & Derivatives;Inhibitors;CARBOHYDRATE;Pharmaceutical Intermediates;Intermediates & Fine Chemicals;Pharmaceuticals;Sugars, Carbohydrates & Glucosides
Mol File:28697-53-2.mol
D(-)-Arabinose Chemical Properties
Melting point 162-164 °C(lit.)
alpha -103.5 º (c=4, H2O, 24hrs.)
Boiling point 191.65°C (rough estimate)
density 1.1897 (rough estimate)
refractive index 1.3920 (estimate)
storage temp. Sealed in dry,2-8°C
solubility H2O: 1 M at 20 °C, clear, colorless
pka12.26±0.70(Predicted)
form Liquid
color Clear
Water Solubility soluble
Stability:Hygroscopic
CAS DataBase Reference28697-53-2(CAS DataBase Reference)
Safety Information
Safety Statements 24/25
WGK Germany 3
3-10
HS Code 29400090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
D(-)-Arabinose Usage And Synthesis
Chemical PropertiesWhite to off-white powder
UsesAn inhibitor of the enzyme glucose dehydrogenase.
Purification MethodsCrystallise D-(-)-arabinose three times from EtOH, dry it in vacuo at 60o for 24hours and store it in a vacuum desiccator. It also crystallises from a mixture of H2O/MeOH/EtOH with m 158-160o, or H2O with m 160-161o. [Whistler & Schweiger J Am Chem Soc 81 5190 1959, Fletcher et al. J Am Chem Soc 72 4546 1950, Beilstein 1 IV 4215, see Angyal Adv Carbohydrate Chem Biochem 42 15 1984 for ratio of anomers in solution.]
D(-)-Arabinose Preparation Products And Raw materials
Raw materialsHydrogen peroxide-->Calcium gluconate
Preparation Productsbeta-D-(-)-Arabinose-->D-ARABINO-1,4-LACTONE

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