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| Methyl 2-iodobenzoate Basic information |
| Methyl 2-iodobenzoate Chemical Properties |
| Melting point | 64°C | | Boiling point | 149-150 °C/10 mmHg (lit.) | | density | 1.784 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.604(lit.) | | Fp | >230 °F | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | solubility | Chloroform, Ethyl Acetate (Slightly), Methanol | | form | Crystalling or Flaky Powder | | color | White | | Water Solubility | INSOLUBLE | | Sensitive | Light Sensitive | | BRN | 2206859 | | Stability: | Light Sensitive | | InChIKey | BXXLTVBTDZXPTN-UHFFFAOYSA-N | | CAS DataBase Reference | 610-97-9(CAS DataBase Reference) | | NIST Chemistry Reference | Methyl-2-iodobenzoate(610-97-9) | | EPA Substance Registry System | Benzoic acid, 2-iodo-, methyl ester (610-97-9) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36-24/25 | | WGK Germany | 3 | | TSCA | T | | HazardClass | IRRITANT | | HS Code | 29163990 |
| Methyl 2-iodobenzoate Usage And Synthesis |
| Chemical Properties | CLEAR YELLOW LIQUID | | Uses | Methyl 2-iodobenzoate may be used in the preparation of:- N-substituted 4-methylene-3,4-dihydro-1(2H)-isoquinolin-1-ones
- methyl diphenylacetylene-2-carboxylate
- methyl 2-heptynylphenylbenzoate
- (E)-2-[3-[3-[2-(7-chloro-2-quinolinyl)ethenyl]phenyl]-3-oxopropyl]benzoic acid methyl ester
- 4-(2-carbomethoxyphenyl)-3-(1-methylethoxy)cyclobut-3-ene-1,2-dione
- 3-(2-carbomethoxyphenyl)-4-methylcyclobuten-3-ene-1,2-dione 2-(ethylene acetal)
| | Synthesis Reference(s) | Journal of the American Chemical Society, 93, p. 4845, 1971 DOI: 10.1021/ja00748a030 | | General Description | Methyl 2-iodobenzoate can be prepared from 2-iodobenzoic acid via esterification. It undergoes cobalt-catalyzed cyclization with aldehydes to form phthalide derivatives. The microbial dihydroxylation of methyl 2-iodobenzoate forms a nonracemic iodocyclohexene carboxylate intermediate. This intermediate forms the precursor for preparing kibdelone C. |
| Methyl 2-iodobenzoate Preparation Products And Raw materials |
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