(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

CAS No.：135620-04-1

Other grades of this product :

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Basic information

Reaction

Product Name:	(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
Synonyms:	(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL;(S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL;(1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride;(S,S)-Jacobsencat.;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(S,S)-JacobsenCat.;(S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco;(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo;(1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat.
CAS:	135620-04-1
MF:	C36H52ClMnN2O2
MW:	635.2
EINECS:
Product Categories:	Chiral Reagents;Jacobsen Metal;Other Metal
Mol File:	135620-04-1.mol

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Chemical Properties

Melting point	330-332 °C(lit.)
storage temp.	Inert atmosphere,Room Temperature
form	Powder
color	brown
InChIKey	VGAJDQCIDNCJQC-JINVCYSXSA-K
CAS DataBase Reference	135620-04-1

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38-20/21/22
Safety Statements	26-36-36/37/39
WGK Germany	3
F	9
HS Code	29310099

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Usage And Synthesis

Reaction	Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess. Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions. Asymmetric Kinetic resolution of secondary alcohols in water. Enantioselective Reformatsky reaction with ketones.
Chemical Properties	dark brown powder

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Preparation Products And Raw materials

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