| DIMETHYL PHOSPHOROCHLORIDATE Basic information |
| Product Name: | DIMETHYL PHOSPHOROCHLORIDATE |
| Synonyms: | DIMETHYL CHLOROPHOSPHATE;DIMETHYL PHOSPHOROCHLORIDATE;Chlorodimethoxyphosphine oxide;Chlorodimethylphosphate;Dimethoxyphosphinic chloride;Dimethyl chloridophosphate;Dimethyl chlorophosphonate;Dimethyl phosphorchloridate |
| CAS: | 813-77-4 |
| MF: | C2H6ClO3P |
| MW: | 144.49 |
| EINECS: | |
| Product Categories: | Aliphatics;Phospholipids - 13C & 2H;Phosphorylating and Phosphitylating Agents |
| Mol File: | 813-77-4.mol |
| DIMETHYL PHOSPHOROCHLORIDATE Chemical Properties |
| Boiling point | 80 °C/25 mmHg (lit.) |
| density | 1.34 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | >230 °F |
| form | clear liquid |
| color | Colorless to Almost colorless |
| CAS DataBase Reference | 813-77-4 |
| Safety Information |
| Hazard Codes | T+ |
| Risk Statements | 26/27/28-34 |
| Safety Statements | 26-36/37/39-45-7/9 |
| RIDADR | UN 2927 6.1/PG 1 |
| WGK Germany | 3 |
| HS Code | 29199000 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| DIMETHYL PHOSPHOROCHLORIDATE Usage And Synthesis |
| Chemical Properties | Clear Liquid |
| Uses | A phosphorylating agent |
| Uses | Dimethyl chlorophosphate may be used for the preparation of (E)-3-cyanophosphoenolpyruvate, by reaction with the potassium enolate of ethyl cyanopyruvate. It may be used for the synthesis of mono- and diphosphate esters of 2-arachidonyl glyceryl ether. |
| Synthesis Reference(s) | Canadian Journal of Chemistry, 34, p. 1819, 1956 DOI: 10.1139/v56-235Synthetic Communications, 23, p. 1771, 1993 DOI: 10.1080/00397919308011275 |
| DIMETHYL PHOSPHOROCHLORIDATE Preparation Products And Raw materials |
| Raw materials | Ethanol-->Hydrogen-->Dimethyl phosphite-->DIMETHYLCHLOROPHOSPHITE-->Methanol-->Carbon tetrachloride-->Sodium methoxide-->Trimethyl phosphite-->Tin tetrachloride-->Trichloroacetonitrile |
| Preparation Products | N-methyl-N-methylsulfonyl-methanesulfonamide-->DIMETHYL-P-NITROPHENYLPHOSPHATE-->FENCHLORPHOS-OXON |
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