Product

Methyl o-toluate

CAS No.：89-71-4

Other grades of this product :

Methyl o-toluate Basic information

Product Name:	Methyl o-toluate
Synonyms:	O-TOLUIC ACID METHYL ESTER;RARECHEM AL BF 0047;2-METHYLBENZOIC ACID METHYL ESTER;2-METHYL METHYLBENZOATE;METHYL-O-METHYL BENZOATE;METHYL O-TOLUATE;METHYL 2-TOLUATE;METHYL 2-METHYLBENZOATE
CAS:	89-71-4
MF:	C9H10O2
MW:	150.17
EINECS:	201-932-2
Product Categories:	Building Blocks;C8 to C9;Carbonyl Compounds;Chemical Synthesis;Esters;Organic Building Blocks;CARBOXYLICESTER;Aromatic Esters
Mol File:	89-71-4.mol

Methyl o-toluate Chemical Properties

Melting point
Boiling point	207-208 °C (lit.)
density	1.073 g/mL at 25 °C (lit.)
vapor pressure	12.9Pa at 23℃
refractive index	1.518-1.52
Fp	82 °C
storage temp.	Sealed in dry,Room Temperature
form	Liquid
color	Clear colorless
Water Solubility	Not miscible or difficult to mix in water.
BRN	2041846
InChIKey	WVWZECQNFWFVFW-UHFFFAOYSA-N
LogP	3 at 25℃
CAS DataBase Reference	89-71-4(CAS DataBase Reference)
NIST Chemistry Reference	Benzoic acid, 2-methyl-, methyl ester(89-71-4)
EPA Substance Registry System	Benzoic acid, 2-methyl-, methyl ester (89-71-4)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	37/39-26-36
WGK Germany	3
TSCA	Yes
HazardClass	IRRITANT
HS Code	29163990

MSDS Information

Provider	Language
Methyl 2-methylbenzoate	English
ACROS	English
ALFA	English

Methyl o-toluate Usage And Synthesis

Chemical Properties	clear colorless liquid
Uses	It has been used in the preparation of 2-(azidomethyl)benzoic acid.
Synthesis Reference(s)	Chemistry Letters, 15, p. 851, 1986Tetrahedron Letters, 24, p. 5181, 1983 DOI: 10.1016/S0040-4039(00)88391-4
General Description	Efficiency of reduction of methyl 2-methylbenzoate using different heterogeneous systems has been compared.
Flammability and Explosibility	Nonflammable

Methyl o-toluate Preparation Products And Raw materials

Preparation Products

Bensulfuron methyl-->2-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID-->METHYL 2-((PIPERIDIN-4-YL)METHYL)BENZOATE-->2-Phenyl-1,2,3,4-tetrahydronaphthalene-->Methyl 2-chloromethylbenzoate-->Methyl 2-methyl-3-nitrobenzoate-->Methyl 2-bromomethylbenzoate-->2-Methyl-3-nitrobenzoic acid-->o-Toluic hydrazide-->3-OXO-3-O-TOLYL-PROPIONIC ACID ETHYL ESTER-->3,5-Dinitro-2-methylbenzoic acid-->METHYL 2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZOATE-->Methyl 5-nitro-2-methylbenzoate-->2-Methylbenzyl alcohol-->METHYL 2-(2-AMINOETHYL)BENZOATE-->Dibenz[b,e]oxepin-11(6H)-one-->methyl 5-bromo-2-methyl-benzoate-->4-Oxo-9,10-dihydro-4H-benzo(4,5)-cyclohepta-(1,2b)thiophene

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