Trimethyl thiazole

Trimethyl thiazole
  • CAS No.:13623-11-5
Other grades of this product :
Trimethyl thiazole Basic information
Description References
Product Name:Trimethyl thiazole
Synonyms:2,4,5-TRIMETHYLTHIAZOLE;FEMA 3325;FEMA NUMBER 3325;TRIMETHYLTHIAZOLE;TRIMETHYL(2,4,5-) THIAZOLE;2,4,5-Trimethyl-1,3-thiazole;2,4,5-trimethyl-thiazol;2 4 5-TRIMETHYLTHIAZOLE 98+%
CAS:13623-11-5
MF:C6H9NS
MW:127.21
EINECS:237-107-9
Product Categories:Building Blocks;Heterocyclic Building Blocks;Thiazoles;Alphabetical Listings;Flavors and Fragrances;Q-Z;thiazole Flavor
Mol File:13623-11-5.mol
Trimethyl thiazole Chemical Properties
Melting point -32.4°C
Boiling point 166-167 °C/717 mmHg (lit.)
density 1.013 g/mL at 25 °C (lit.)
refractive index n20/D 1.509(lit.)
FEMA 3325 | 2,4,5-TRIMETHYLTHIAZOLE
Fp 133 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pkapK1:4.55 (25°C,μ=0.1)
form liquid
Specific Gravity1.311.013
color Light orange to Yellow to Green
JECFA Number1036
BRN 107148
CAS DataBase Reference13623-11-5(CAS DataBase Reference)
NIST Chemistry ReferenceThiazole, 2,4,5-trimethyl-(13623-11-5)
EPA Substance Registry SystemThiazole, trimethyl- (13623-11-5)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-37/38-41-36/37/38
Safety Statements 26-39-37/39-36-7/9
RIDADR UN 1993 3/PG 3
WGK Germany 3
TSCA Yes
HazardClass 3.2
PackingGroup III
HS Code 29339900
MSDS Information
ProviderLanguage
Trimethyl thiazole English
ACROS English
SigmaAldrich English
ALFA English
Trimethyl thiazole Usage And Synthesis
Description2,4,5-trimethyl thiazole has a cocoa, dark chocolate, nutty, coffee note. It is naturally found in cooked potatoes, cooked meat, coffee, black tea, and herbs. It is used as a flavor ingredient in foods.
References[1] George A. Burdock, Encyclopedia of Food and Color Additives, Volume 3, 1997 [2] Erich Ziegler and Herta Ziegler, Flavourings: Production, Composition, Applications, Regulations, 1998
Chemical Propertiesclear colourless to yellow liquid
Chemical Properties2,4,5-Trimethyl thiazole has a cocoa, dark chocolate, nutty, coffee taste.
OccurrenceReported found in kohlrabi, French fried potato, boiled and cooked potato, fried chicken, raw chicken, boiled and cooked beef, grilled and roasted beef, lamb and mutton liver, boiled and cooked cured pork, coffee, black tea, coriander seed, katsuobushi (dried bonito), cooked shrimp and other natural sources.
Uses2,4,5-Trimethylthiazole was employed as internal standard in the gas chromatographic determination of aldehydes in alcoholic beverages.
PreparationBy decarboxylation of 2,4-dimethylthiazole-5-acetic acid; by reacting acetamide and phosphorous pentasulfide with methyl-α-bromoethyl ketone.
DefinitionChEBI: A 1,3-thiazole that is thiazole in which all three hydrogens are replaced by methyl groups. A Maillard reaction product, it is a flavour component in many cooked foods, including cooked meats and potatoes.
Aroma threshold valuesDetection: 50 ppb
Taste threshold valuesTaste characteristics at 10 ppm: nutty, cocoa and green vegetative-like with roasted earthy nuances.
General Description2,4,5-Trimethylthiazole is a volatile oxidant and was isolated during microwave-induced L-cysteine/D-glucose Maillard model system.

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