3-Methoxycarbonylphenylboronic acid

3-Methoxycarbonylphenylboronic acid
  • CAS No.:99769-19-4
Other grades of this product :
3-Methoxycarbonylphenylboronic acid Basic information
Product Name:3-Methoxycarbonylphenylboronic acid
Synonyms:METHYL 3-BORONOBENZOATE;3-METHOXYCARBONYLPHENYLBORONIC ACID;3-(METHOXYCARBONYL)BENZENEBORONIC ACID;AKOS BRN-0125;M-(METHOXYCARBONYL)PHENYLBORONIC ACID;3-METHOXYCARBONYLPHENYLBARONIC ACID;3-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride);3-Methoxycarbonylphenylboronic acid,97%
CAS:99769-19-4
MF:C8H9BO4
MW:179.97
EINECS:
Product Categories:Aromatics;Boron Derivatives;Intermediates & Fine Chemicals;Pharmaceuticals;Boronate Ester;Potassium Trifluoroborate;Acids and Derivatives;Boron, Nitrile, Thio,& TM-Cpds;Boronic acids;Aryl;Ester;Organoborons;B (Classes of Boron Compounds);Boronic acid;blocks;BoronicAcids;Carboxes;CHIRAL CHEMICALS
Mol File:99769-19-4.mol
3-Methoxycarbonylphenylboronic acid Chemical Properties
Melting point 205-208 °C(lit.)
Boiling point 359.9±44.0 °C(Predicted)
density 1.25±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka7.74±0.10(Predicted)
form Powder
color White to off-white
Water Solubility Reacts with water.
InChIKeyALTLCJHSJMGSLT-UHFFFAOYSA-N
CAS DataBase Reference99769-19-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26-36
WGK Germany 3
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
3-Methoxycarbonylphenylboronic acid Usage And Synthesis
Chemical PropertiesWhite to light yellow crystal powde
Uses3-Methoxycarbonylphenylboronic acid can be used in the preparation of substituted pyrazolylpyrimidinamine derivative for use as protein kinase inhibitors and suzuki reaction.
Usessuzuki reaction
UsesReagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration, cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. Reagent used in Preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6, chromenones and their bradykinin B1 antagonistic active, Pt nanoparticles at Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injecti, salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.
3-Methoxycarbonylphenylboronic acid Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->Magnesium-->Triisopropyl borate-->Bis(2-dimethylaminoethyl) ether-->Methyl 3-iodobenzoate

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