(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE

(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
  • CAS No.:447440-43-9
Other grades of this product :
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Basic information
Reaction
Product Name:(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE
Synonyms:(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane ;(4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-prop-2-enyl-1,3,2-oxazasilolidine;(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine;1-Oxa-3-aza-2-silacyclopentane,2-chloro-3,4-dimethyl-5-pheny...
CAS:447440-43-9
MF:C13H18ClNOSi
MW:267.83
EINECS:
Product Categories:organosilicon compound
Mol File:447440-43-9.mol
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Chemical Properties
density 1.095 g/mL at 25 °C
refractive index n20/D1.517
Fp 38℃
Specific Gravity1.01
optical activity[α]20/D 72.5°, c = 0.6 in ethanol (200 proof)
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Sensitive moisture sensitive, store cold
Boiling point 120°C/5 mmHg
Safety Information
Hazard Codes F,Xi
Risk Statements 10-15-36/37/38
Safety Statements 26
RIDADR UN 3132 / PGII
WGK Germany 3
MSDS Information
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Usage And Synthesis
ReactionVersatile reagent for the enantioselective allylation of aldehydes and hydrazones.
UsesLeighton′s Strained Silacycles: Powerful Enantioselective Allylation Reagents
  • Practical, enantioselective allylation of acylhydrazones
  • Enantioselective allylation of ketimines: synthesis of tertiary carbinamines
General DescriptionThis product is a mixture of diastereomers.
(s,s)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE Preparation Products And Raw materials

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