| (4S)-(-)-4-Isopropyl-2-oxazolidinone Basic information |
| Product Name: | (4S)-(-)-4-Isopropyl-2-oxazolidinone |
| Synonyms: | (4S)-4β-Isopropyloxazolidine-2-one;(S)-4-Isopropyloxazolidine-2-one;(S)-4β-Isopropyloxazolidine-2-one;4β-Isopropyloxazolidine-2-one;(4S)-(-)-4-Isopropyl-2-oxazolidinone,98%;(S)-4-isopropyl-2-1xazolidinone;(4S)-(-)-4-Isopropyl;(4S)-4-(Prop-2-yl)-1,3-oxazolidin-2-one |
| CAS: | 17016-83-0 |
| MF: | C6H11NO2 |
| MW: | 129.16 |
| EINECS: | 640-491-4 |
| Product Categories: | Chiral Reagents;Asymmetric Synthesis;Chiral Building Blocks;Glycidyl Compounds, etc. (Chiral);Synthetic Organic Chemistry;Peptide;Oxazolidinone;chiral;Asymmetric Synthesis;Chiral Auxiliaries;Oxazolidinone Derivatives |
| Mol File: | 17016-83-0.mol |
| (4S)-(-)-4-Isopropyl-2-oxazolidinone Chemical Properties |
| Melting point | 70-73 °C(lit.) |
| alpha | -18 º (c=1, ethanol) |
| Boiling point | 239.22°C (rough estimate) |
| density | 1.1426 (rough estimate) |
| refractive index | -17.5 ° (C=6, EtOH) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform, Dichloromethane, Ethanol |
| pka | 12.72±0.40(Predicted) |
| form | Crystalline Powder |
| color | White |
| optical activity | [α]20/D 18°, c = 6 in ethanol |
| Water Solubility | Insoluble |
| BRN | 3588198 |
| CAS DataBase Reference | 17016-83-0(CAS DataBase Reference) |
| NIST Chemistry Reference | (S)-(+)-4-isopropyl-2-oxazolidinone(17016-83-0) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 22-24/25-36-26 |
| WGK Germany | 3 |
| F | 3 |
| HS Code | 29349990 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| (4S)-(-)-4-Isopropyl-2-oxazolidinone Usage And Synthesis |
| Chemical Properties | White to off-White Solid |
| Uses | Reagent employed as a chiral ligand in dirhodium(II) complexes and as a chiral auxiliary in aldol addition reactions. Versatile chiral auxiliary for asymmetric synthesis. For a recent review, see Aldrichimica Acta. |
| (4S)-(-)-4-Isopropyl-2-oxazolidinone Preparation Products And Raw materials |
| Raw materials | (R)-(+)-4-Isopropyl-2-oxazolidinone |
| Preparation Products | (S)-(+)-4-Isopropyl-3-propionyl-2-oxazolidinone-->(R)-(-)-2-Phenylpropionic acid |
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