Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

CAS No.：35138-22-8

Other grades of this product :

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Basic information

Uses

Product Name:	Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Synonyms:	Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate;ooctadiene)rhodium(Ⅰ)tetrafL;(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX;Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE
CAS:	35138-22-8
MF:	C16H24BF4Rh
MW:	406.07
EINECS:	460-220-1
Product Categories:	Rh;organometallic complex
Mol File:	35138-22-8.mol

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties

Melting point	210 °C
density	0.42 g/cm3 (20℃)
storage temp.	Inert atmosphere,Store in freezer, under -20°C
form	Powder
color	Red
PH	7 (5g/l, H2O, 20℃)
Water Solubility	insoluble
Sensitive	Slightly air & moisture sensitive
Exposure limits	ACGIH: TWA 1 mg/m3NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey	IEMMJJILGGBYNZ-GSLAGHMSSA-M
CAS DataBase Reference	35138-22-8(CAS DataBase Reference)

Safety Information

Hazard Codes	F,Xi
Risk Statements	11-34
Safety Statements	16-45-36/37/39-26
RIDADR	UN 2921
WGK Germany	2
Hazard Note	Irritant
TSCA	No
HazardClass	8
PackingGroup	III
HS Code	28439000

MSDS Information

Provider	Language
ACROS	English
ALFA	English

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Usage And Synthesis

Uses	Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations. Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions.
Chemical Properties	dark red
Uses	Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials

Raw materials

Ethanol-->Ethyl acetate-->1,5-Cyclooctadiene-->Silver tetrafluoroborate-->Rhodium(III) chloride hydrate-->BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE-->Ammonium fluoborate

Welcome！

Please leave a message for us or use the following ways to contact us, we will reply to you as soon as possible, and provide you with the most sincere service, thank you.

NO. 18 ,Wujiang Road, Wulidian Street, Jiangbei District, Chongqing
+86-23-6139-8061 +86-13650506873
danny@chemdad.com sales@chemdad.com
www.chemdad.com
WhatsApp +86-13650506873