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| GAMMA-CHLOROBUTYROPHENONE Basic information |
| Product Name: | GAMMA-CHLOROBUTYROPHENONE | | Synonyms: | 1-Butanone, 4-chloro-1-phenyl-;omega-Chlorobutyrophenone;GAMMA-CHLOROBUTYROPHENONE;4-CHLOROBUTYROPHENONE, TECH.;z-Chlorobutyrophenone;4-Chloro-1-phenylbutane-1-one;4-Chlorobutyrophenone,95%;3-chloropropyl phenyl ketone | | CAS: | 939-52-6 | | MF: | C10H11ClO | | MW: | 182.65 | | EINECS: | 213-362-1 | | Product Categories: | | Mol File: | 939-52-6.mol |
| GAMMA-CHLOROBUTYROPHENONE Chemical Properties |
| Melting point | 19-20 °C (lit.) | | Boiling point | 130-133 °C4 mm Hg | | density | 1.137 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.544(lit.) | | Fp | >230 °F | | BRN | 878974 | | CAS DataBase Reference | 939-52-6(CAS DataBase Reference) |
| Hazard Codes | Xi | | Safety Statements | 23-24/25 | | RIDADR | UN 2927 6.1/PG 1 | | WGK Germany | 3 | | HS Code | 2914790090 |
| GAMMA-CHLOROBUTYROPHENONE Usage And Synthesis |
| Uses | 4-Chlorobutyrophenone may be used in the preparation of silyl enol ether, Z-4-chloro-1-phenyl-1-trimethylsilyloxybut-1-ene. It may be used as starting material in the preparation of 8-arylimidazopyridines. | | Synthesis Reference(s) | Journal of the American Chemical Society, 79, p. 1455, 1957 DOI: 10.1021/ja01563a049 | | General Description | 4-Chlorobutyrophenone is a chloro ketone. Preparation of 4-chlorobutyrophenone is reported. | | Purification Methods | Fractionate the ketone several times using a short column. It recrystallises from pet ether at -20o as glistening white rosettes and is filtered at 0o, and dried in a vacuum desiccator over H2SO4. The semicarbazone has m 136-137o. [Conant et al. J Am Chem Soc 46 1882 1924, Cloke J Chem Soc 1174 1929, Hart & Curtis J Am Chem Soc 79 931 1957, Beilstein 7 IV 711.] |
| GAMMA-CHLOROBUTYROPHENONE Preparation Products And Raw materials |
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