Other grades of this product :
| BENZANILIDE Basic information |
| BENZANILIDE Chemical Properties |
| Melting point | 161-163 °C(lit.) | | Boiling point | 117 °C10 mm Hg(lit.) | | density | 1,315 g/cm3 | | refractive index | 1.6050 (estimate) | | Fp | 117°C/10mm | | storage temp. | Store below +30°C. | | solubility | H2O: insoluble | | Colour Index | 42095 | | pka | 13.52±0.70(Predicted) | | form | Powder | | color | Grayish to yellow-green | | Water Solubility | Insoluble | | Merck | 14,1061 | | BRN | 1102980 | | CAS DataBase Reference | 93-98-1(CAS DataBase Reference) | | NIST Chemistry Reference | N-Phenylbenzoic acid amide(93-98-1) | | EPA Substance Registry System | Benzanilide (93-98-1) |
| BENZANILIDE Usage And Synthesis |
| Chemical Properties | greyish to yellow-green powder | | Uses | manufacture of dyes and perfumes. | | Uses | Benzanilide is used to make dyes, active pharmaceutical ingredients and perfumes. It is also used to study the influence of beta-cyclodextrin on photorearrangement of acetanilide, benzanilide and ethyl phenyl carbonate. Further, it is used as an amide model compound to study the reaction between the amide and epoxy. In addition to this, it reacts with aryltriflates in the presence of palladium-based catalyst system to get N-(2,6-diarylbenzoyl)anilines. | | Synthesis Reference(s) | Journal of Heterocyclic Chemistry, 24, p. 187, 1987 DOI: 10.1002/jhet.5570240135The Journal of Organic Chemistry, 20, p. 1482, 1955 DOI: 10.1021/jo01128a004Tetrahedron Letters, 31, p. 1063, 1990 DOI: 10.1016/S0040-4039(00)94431-9 | | General Description | Benzanilide undergoes diarylation with aryl triflates or bromides in the presence of a palladium-based catalyst system to form corresponding N-(2,6-diarylbenzoyl)anilines. It is used in manufacture of dyes and perfumes. | | Purification Methods | Crystallise benzanilide from pet ether (b 70-90o) using a Soxhlet extractor, and dry it overnight at 120o. Also crystallise it from EtOH. [Beilstein 12 IV 417.] |
| BENZANILIDE Preparation Products And Raw materials |
|
日本语
한국어
Français
Deutsch
España
Türkiye