2-Allylcyclohexanone

CAS No.：94-66-6

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2-Allylcyclohexanone Basic information

Product Name:	2-Allylcyclohexanone
Synonyms:	2-ALLYLCYCLOHEXANONE;2-(2-PROPENYL)CYCLOHEXANONE;TIMTEC-BB SBB006544;O-ALLYLCYCLOHEXANONE;2-(2-propenyl)-cyclohexanon;Cyclohexanone, 2-allyl-;2-allylcyclohexan-1-one;2-Allylcyclohexanone, 97% 1GR
CAS:	94-66-6
MF:	C9H14O
MW:	138.21
EINECS:	202-352-2
Product Categories:	C9;Carbonyl Compounds;Ketones
Mol File:	94-66-6.mol

2-Allylcyclohexanone Chemical Properties

Boiling point	94 °C/23 mmHg (lit.)
density	0.927 g/mL at 25 °C (lit.)
refractive index	n20/D 1.469(lit.)
Fp	>230 °F
form	clear liquid
Specific Gravity	0.927
color	Colorless to Light yellow to Light orange
Water Solubility	Insoluble
CAS DataBase Reference	94-66-6(CAS DataBase Reference)
NIST Chemistry Reference	Cyclohexanone, 2-(2-propenyl)-(94-66-6)
EPA Substance Registry System	Cyclohexanone, 2-(2-propenyl)- (94-66-6)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	20/21/22-36/37/38
Safety Statements	22-26-36/37/39-45-37/39
RIDADR	UN 3077
WGK Germany	3
HS Code	29142990

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

2-Allylcyclohexanone Usage And Synthesis

Chemical Properties	clear light yellow liquid
Uses	2-Allylcyclohexanone may be used in the synthesis of the following: bicyclo[3.3.1]non-2-en-9-one R-(-)-epilachnene, an antipode of the defensive droplets from the Mexican bean beetle, Epilachna varivestis
Synthesis Reference(s)	Chemistry Letters, 13, p. 1721, 1984Journal of the American Chemical Society, 85, p. 207, 1963 DOI: 10.1021/ja00885a021The Journal of Organic Chemistry, 51, p. 421, 1986 DOI: 10.1021/jo00354a001
General Description	2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied.

2-Allylcyclohexanone Preparation Products And Raw materials

Raw materials

Potassium hydroxide-->Benzotrifluoride-->3-propan-2-yloxyprop-1-ene-->Carbonic acid, 1-cyclohexen-1-yl 2-propen-1-yl ester-->Stannane, tributyl(1-cyclohexen-1-yloxy)--->Cyclohexane, (2-propen-1-yloxy)--->ALLYL N-PROPYL ETHER-->Allyl 2-Oxocyclohexanecarboxylate-->N-(1-Cyclohexen-1-yl)morpholine-->1-Pyrrolidino-1-cyclohexene-->Allyl Benzyl Ether-->ALLYL ETHYL ETHER-->ALLYL METHYL ETHER-->Allyl acetate-->Allyl phenyl ether-->Allyl bromide

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