(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)

CAS No.：172138-95-3

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(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Basic information

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Product Name:	(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
Synonyms:	1S,2S- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide);2,6-Bis[(4S)-benzyl-2-oxazolin-2-yl]-pyridine;(+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),min.98%;(+)-N,N''-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE), MIN. 98%;N-((1S,2S)-2-(picolinamido)cyclohexyl)picolinamide;(1S,2S)-N,Nμ-1,2-Cyclohexanediylbis(2-pyridinecarboxamide), (+)-N,Nμ-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), (1S,2S)-(+)-1,2-Bis[(2-pyridinylcarbonyl)amino]cyclohexane, (1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane;(S,S)-DACH-pyridyl Trost ligand;(1R,2R)-(-)-1,2-Bis[(2-pyridinylcarbonyl)amino]cyclohexane
CAS:	172138-95-3
MF:	C18H20N4O2
MW:	324.38
EINECS:
Product Categories:	Chiral Nitrogen;DACH&Trost Series
Mol File:	172138-95-3.mol

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Chemical Properties

Melting point	170°C
alpha	+95° (c 1, CH3OH)
Boiling point	663.4±50.0 °C(Predicted)
density	1.25±0.1 g/cm3(Predicted)
storage temp.	Inert atmosphere,2-8°C
pka	12.51±0.40(Predicted)
form	Powder
color	off-white
CAS DataBase Reference	172138-95-3

Safety Information

Hazard Codes	Xn
Risk Statements	36/37/38-22
Safety Statements	26-36/37/39-36/37
WGK Germany	3

MSDS Information

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Usage And Synthesis

Reactions	Ligands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pending Stanford University patents. Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers
Uses	Trost Ligands for Asymmetric Allylic Alkylation

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Preparation Products And Raw materials

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