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| Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Basic information | | Reaction |
| Product Name: | Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate | | Synonyms: | Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulphonate99%;Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;BIS(1,5-CYCLOOCTADIENE)-TRIFLUOROMETHANESULFITORHODIUM (I);BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TRIFL&;Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate,99%;Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethane sulphonate 99%;Bis(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate 98% | | CAS: | 99326-34-8 | | MF: | C17H24F3O3RhS | | MW: | 468.34 | | EINECS: | | Product Categories: | Rh;organometallic complex;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium | | Mol File: | 99326-34-8.mol |
| Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Chemical Properties |
| Melting point | 159 °C (dec.)(lit.) | | storage temp. | Inert atmosphere,Room Temperature | | solubility | Soluble in chloroform | | form | crystal | | color | dark red | | Water Solubility | insoluble | | Sensitive | Air Sensitive | | Exposure limits | ACGIH: TWA 1 mg/m3NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | Hazard Note | Irritant | | TSCA | No | | HS Code | 28439000 |
| Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Usage And Synthesis |
| Reaction |
- Rhodium catalyzed contrasteric regiocontrolled hydrogenative couplings of nonsymmetric 1,3-diynes to ethyl glyoxalate
- Rhodium catalyzed reductive Mannich coupling of vinyl ketones to N-Sulfonylimines mediated by hydrogen
- Rhodium catalyzed asymmetric synthesis of Sitagliptin
- Rhodium catalyzed asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones
| | Chemical Properties | dark red crystals | | Uses | Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis |
| Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Preparation Products And Raw materials |
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