Piperonyloyl chloride

Piperonyloyl chloride
  • CAS No.:25054-53-9
Other grades of this product :
Piperonyloyl chloride Basic information
Product Name:Piperonyloyl chloride
Synonyms:BUTTPARK 154\04-36;3,4-(METHYLENEDIOXY)BENZOYL CHLORIDE;TIMTEC-BB SBB003720;PIPERONYLOYL CHLORIDE;1,3-BENZODIOXOLE-5-CARBONYL CHLORIDE;Benzo[d][1,3]dioxole-5-carbonyl chloride;1,3-Benzodioxole-5-carbonyl chloride (9CI);Piperonoyl chloride
CAS:25054-53-9
MF:C8H5ClO3
MW:184.58
EINECS:
Product Categories:ACIDHALIDE;Acid Halides;Carbonyl Compounds;Organic Building Blocks;Acid Halides;Building Blocks;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
Mol File:25054-53-9.mol
Piperonyloyl chloride Chemical Properties
Melting point 78-79 °C (lit.)
Boiling point 155 °C/25 mmHg (lit.)
density 1.3964 (estimate)
storage temp. Hygroscopic, Refrigerator, under inert atmosphere
solubility Chloroform (Slightly)
form Crystalline Powder
color Off-white to blue-gray
Stability:Moisture Sensitive, reacts with Moisture in the air
CAS DataBase Reference25054-53-9(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 22-26-27-28-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
Hazard Note Corrosive
HazardClass 8
PackingGroup III
HS Code 29329900
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Piperonyloyl chloride Usage And Synthesis
Chemical Propertiesoff-white to blue-grey crystalline powder
UsesPiperonyloyl chloride is suitable for use in a kinetic study to evaluate the solvolysis rate constants of piperonyloyl chloride in 27 different solvents. It may be used in the synthesis of the following compounds:
  • 2-phenylbenzimidazoles
  • (Z)-3-hydroxy-1-(5-methoxy-2,2-dimethyl-2H-chromen-6-yl)-3-phenylprop-2-en-1-one
  • pongapinone A
  • 2-((1-(2-(N-(4-chlorophenyl)benzo[d][1,3]dioxole-5-carboxamido)ethyl)piperidin-4-yl)oxy)acetic acid phosphoric acid salt, inhibitor of platelet aggregation
  • justicidin B, the piscicidal components of Justicia Hayatai var. decumbens
  • piperazine derivatives
General DescriptionPiperonyloyl chloride is an acyl halide. It participates in the preparation of starting reagent (N-acyl indole), required for the synthesis of pyrrolophenanthridone alkaloids. Kinetic study of the solvolysis of piperonyloyl chloride in various pure and binary solvent mixtures has been proposed. Solvolysis reaction has been reported to proceed via electron-rich acyl transfer mechanism.

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