SILVER CHROMATE

SILVER CHROMATE
  • CAS No.:7784-01-2
Other grades of this product :
SILVER CHROMATE Basic information
Product Name:SILVER CHROMATE
Synonyms:chromicacid(h2cro4),disilver(1++)salt;Chromicacid,disilver(1+)salt;SILVER(I) CHROMATE;SILVER CHROMATE;Silver(I)chromate,99%min;SILVER CHROMATE REAGENT;Silverchromate,99%;silver(I) chromate(VI)
CAS:7784-01-2
MF:AgCrH2O4
MW:225.88
EINECS:232-043-8
Product Categories:Metal and Ceramic Science;Salts;Silver Salts;chromate and dichromate salts
Mol File:7784-01-2.mol
SILVER CHROMATE Chemical Properties
density 5.625 g/mL at 25 °C (lit.)
form Powder
Specific Gravity5.625
color Red-brown
Water Solubility Slightly soluble in water. Soluble in HNO<sub>3</sub> and ammonia
Sensitive Light Sensitive
Merck 14,8510
Solubility Product Constant (Ksp)pKsp: 11.95
Exposure limitsOSHA: Ceiling 0.1 mg/m3NIOSH: IDLH 15 mg/m3; TWA 0.0002 mg/m3
Stability:Stable. but light-sensitive and hygroscopic.
CAS DataBase Reference7784-01-2(CAS DataBase Reference)
EPA Substance Registry SystemChromic acid (H2CrO4), disilver(1+) salt (7784-01-2)
Safety Information
Hazard Codes O,T,N
Risk Statements 8-43-49-50/53
Safety Statements 17-45-53-61-60
RIDADR 3087
WGK Germany 3
TSCA Yes
HazardClass 5.1
PackingGroup III
MSDS Information
ProviderLanguage
ALFA English
SILVER CHROMATE Usage And Synthesis
Chemical Propertiescrystalline powder
Physical propertiesRed monoclinic crystals or brownish-red powder; density 5.625 g/cm3; insoluble in water; soluble in nitric acid, ammonia and solutions of alkali cyanides and chromates.
UsesCatalyst for formation of aldol from alcohol; formed at end point of Mohr titration of halides.
PreparationSilver chromate is prepared by slowly adding a solution of potassium chromate to a solution of silver nitrate:2Ag+ (aq) + Cr4O2- (aq) → Ag2CrO4 (s)The precipitate is washed with hot water.
Purification MethodsWash the red-brown powder with H2O, dry it in a vacuum, then powder well and dry again in a vacuum at 90o/5hours. Its solubility in H2O is 0.0014% at 10o. Store it in the dark. [Cardillo & Shimizu J Org Chem 42 4268 1977.]
SILVER CHROMATE Preparation Products And Raw materials

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