Allylmagnesium chloride

CAS No.：2622-05-1

Important Notice

This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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Allylmagnesium chloride Basic information

Product Name:	Allylmagnesium chloride
Synonyms:	ALLYLMAGNESIUM CHLORIDE;ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN;ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I;ALLYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF;Allylmagnesium chloride 1.5M solution in THF;AllylMagnesiuM chloride, 1.7 M solution in THF, J&KSeal;Allylmagnesium chloride solution;Allyl chlorideMagnesiuM
CAS:	2622-05-1
MF:	C3H5ClMg
MW:	100.83
EINECS:	220-067-1
Product Categories:	Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Alkyl;GRIGNARD REAGENTS;Grignard Reagents;Organometallic Reagents;Grignard Reagent
Mol File:	2622-05-1.mol

Allylmagnesium chloride Chemical Properties

Melting point	-21°C
Boiling point	66°C
density	0.995 g/mL at 25 °C
Fp	1 °F
storage temp.	water-free area
form	Liquid
color	Clear tan to brown, amber, dark gray, dark green or black
Water Solubility	vigorous reaction
Sensitive	Air & Moisture Sensitive
BRN	3587316
InChIKey	PLYLAFITHJUEGX-UHFFFAOYSA-M
EPA Substance Registry System	Magnesium, chloro-2-propenyl- (2622-05-1)

Safety Information

Hazard Codes	F,C
Risk Statements	11-14/15-34-40-37-19
Safety Statements	16-26-36/37/39-43-45-7/8-6A-43B-33
RIDADR	UN 3399 4.3/PG 1
WGK Germany	1
F	1-3-10
TSCA	Yes
HazardClass	4.2
PackingGroup	I
HS Code	29319090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English

Allylmagnesium chloride Usage And Synthesis

Chemical Properties	clear tan to brown, amber, dark grey, dark green
Uses	Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.Grignard-reactions: reagent for the introduction of the allyl group.
Uses	Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Application	Used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins.
Precautions	It reacts violently with water.Air & moisture sensitive. Stable under recommended storage conditions.

Allylmagnesium chloride Preparation Products And Raw materials

Raw materials	Tetrahydrofuran-->Magnesium-->Allyl chloride
Preparation Products	3-METHYL-1,5-HEXADIENE-->1,6-HEPTADIEN-4-OL-->Tetraallyltin-->6-Chlorohex-1-ene

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