| O-TOLYLMAGNESIUM BROMIDE Basic information |
| Product Name: | O-TOLYLMAGNESIUM BROMIDE |
| Synonyms: | 2-METHYLPHENYLMAGNESIUM BROMIDE;O-TOLYLMAGNESIUM BROMIDE;bromo-o-tolylmagnesium;O-TOLYLMAGNESIUM BROMIDE, 2.0M SOLUTION IN DIETHYL ETHER;o-tolylmagnesium bromide solution;O-TOLYLMAGNESIUM BROMIDE: 19% IN THF, 1M/L;o-Tolylmagnesium Bromide (19% in Tetrahydrofuran, ca. 1mol/L);2-Methylphenylbromomagnesium |
| CAS: | 932-31-0 |
| MF: | C7H7BrMg |
| MW: | 195.34 |
| EINECS: | 213-250-2 |
| Product Categories: | Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Aryl;Grignard Reagents;Organometallic Reagents;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals |
| Mol File: | 932-31-0.mol |
| O-TOLYLMAGNESIUM BROMIDE Chemical Properties |
| density | 1.013 g/mL at 25 °C |
| Fp | −40 °F |
| form | Solution |
| color | Gray to brown |
| InChIKey | DVXDIGKNJYSMFM-UHFFFAOYSA-M |
| CAS DataBase Reference | 932-31-0 |
| Safety Information |
| Hazard Codes | F+,C,F |
| Risk Statements | 12-14-20/21/22-34-40-67-22-19-11 |
| Safety Statements | 16-26-33-36/37/39-45 |
| RIDADR | UN 3399 4.3/PG 1 |
| WGK Germany | 3 |
| HazardClass | 3/8 |
| PackingGroup | II |
| HS Code | 29319090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| O-TOLYLMAGNESIUM BROMIDE Usage And Synthesis |
| Chemical Properties | Yellow to brown liquid |
| Uses | 2-Tolylmagnesium Bromide is an intermediate used in the synthesis of 13-Fluorodibenzo[a,i]pyrene (F588440), which is a polycyclic aromatic hydrocarbon (PAH) thus potentially exhibiting carcinogenic properties through activation of P450 mono-oxygenase enzymes. Also, it has unique electrical and optical properties due to being a conjugated macromolecule. |
| O-TOLYLMAGNESIUM BROMIDE Preparation Products And Raw materials |
| Preparation Products | BIS(O-TOLYL)PHOSPHINE-->2-Methylbenzhydryl chloride-->2-Methylbenzene-1-sulfonamide |
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