1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane
  • CAS No.:6737-42-4
Other grades of this product :
melting point63-65 °C (lit.)
boiling point529.7±33.0 °C(Predicted)
flash point235°C
Storage conditionsInert atmosphere,Room Temperature
formGranules or Powder
colourWhite to light yellow-beige
proportion1.7629 (20/4℃)
Water solubilityinsoluble
susceptibilityAir Sensitive
BRN2821785
InChIKeyLVEYOSJUKRVCCF-UHFFFAOYSA-N
CAS6737-42-4
EPA Chemical InformationPhosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)
NIST Chemical information1,3-Bis(diphenylphosphino)propane(6737-42-4)


1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.


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