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| 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Basic information | | Reaction |
| Product Name: | 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL | | Synonyms: | 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL;2,2'-BIS(DIPHENYLPHOSPHINO)BIPHENYL;BIPHEP;[2-(2-diphenylphosphinophenyl)phenyl]-diphenylphosphine;2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98%BIPHEP;2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, (BIPHEP);2,2’-Bis(diphenylphospino)-1,1’-biphenyl;PHOSPHINE, 1,1''-[[1,1''-BIPHENYL]-2,2''-DIYL]BIS[1,1-DIPHENYL- | | CAS: | 84783-64-2 | | MF: | C36H28P2 | | MW: | 522.55 | | EINECS: | | Product Categories: | Achiral Phosphine;Aryl Phosphine;Phosphines;Biphenyl & Diphenyl ether;Phosphine Ligands;Synthetic Organic Chemistry | | Mol File: | 84783-64-2.mol |
| 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties |
| Melting point | 210-214 °C | | Boiling point | 635.5±48.0 °C(Predicted) | | solubility | soluble in Toluene | | form | crystal | | color | white |
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ACROS
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| 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Usage And Synthesis |
| Reaction |
- Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.
- Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions
- Useful ligand for palladium-catalyzed synthesis of butatrenes.
- Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.
- Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.
- Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.
- Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.
- Ruthenium-catalyzed synthesis of indoles.
- Ruthenium-catalyzed oxidative cyclization.
- Rhodium-catalyzed boron arylation.
| | Chemical Properties | white crystalline powder or crystals | | Uses | 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl (CAS# 84783-64-2) is a chelating phosphine and has been used to study the effects of bite angles on the chemical and physical properties of transition metal complexes. 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl appears as a catalytic ligand in Ni- and Pd-Catalyzed cross-electrophile coupling reactions to form highly substituted 1,3-dienes. |
| 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Preparation Products And Raw materials |
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